ArticleNature communications2019
Non-equilibrium crystallization pathways of manganese oxides in aqueous solution.
Article in Nature communications, 2019. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 22 papers.
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Who cites it
22 citing papers in PubMed.
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- Control of Crystallization Pathways in the BiFeOChemistry of materials : a publication of the American Chemical Society · 2025Article
- Proton-exchange induced reactivity in layered oxides for lithium-ion batteries.Nature communications · 2024Article
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- The Chemistry of Spinel Ferrite Nanoparticle Nucleation, Crystallization, and Growth.ACS nano · 2024Article
- Influence of the Precursor Structure on the Formation of Tungsten Oxide Polymorphs.Inorganic chemistry · 2023Article
- Comparative Study of α- and β-MnONanomaterials (Basel, Switzerland) · 2023Article
- Porosity evolution and oxide formation in bulk nanoporous copper dealloyed from a copper-manganese alloy studied byNanoscale advances · 2023Article
- Characterisation of intergrowth in metal oxide materials using structure-mining: the case of γ-MnODalton transactions (Cambridge, England : 2003) · 2022Article
- Calculation of a temperature-volume phase diagram of water to inform the study of isochoric freezing down to cryogenic temperatures.RSC advances · 2022Article
- Dataset of solution-based inorganic materials synthesis procedures extracted from the scientific literature.Scientific data · 2022Article
- Ab initio thermodynamics reveals the nanocomposite structure of ferrihydrite.Communications chemistry · 2021Article
- The interplay between thermodynamics and kinetics in the solid-state synthesis of layered oxides.Nature materials · 2020Article
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Authors and funding
4 authors.
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No grant is acknowledged in the PubMed record.
Abstract
Aqueous precipitation of transition metal oxides often proceeds through non-equilibrium phases, whose appearance cannot be anticipated from traditional phase diagrams. Without a precise understanding of which metastable phases form, or their lifetimes, targeted synthesis of specific metal oxides can become a trial-and-error process. Here, we construct a theoretical framework to reveal the nanoscale and metastable energy landscapes of Pourbaix (E-pH) diagrams, providing quantitative insights into the size-dependent thermodynamics of metastable oxide nucleation and growth in water. By combining this framework with classical nucleation theory, we interrogate how solution conditions influence the multistage oxidation pathways of manganese oxides. We calculate that even within the same stability region of a Pourbaix diagram, subtle variations in pH and redox potential can redirect a non-equilibrium crystallization pathway through different metastable intermediates. Our theoretical framework offers a predictive platform to navigate through the thermodynamic and kinetic energy landscape towards the rational synthesis of target materials.
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