ArticleChemical science2019
Controllably realizing elastic/plastic bending based on a room-temperature phosphorescent waveguiding organic crystal.
Article in Chemical science, 2019. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 22 papers.
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Who cites it
22 citing papers in PubMed.
- Structural Origin of Crystallographic Face-Dependent Elastoplastic and Plastic Bending in an Organic Molecular Crystal.Chemistry (Weinheim an der Bergstrasse, Germany) · 2026Article
- Resonator-based add-drop filters enabled by flexible polymorphic crystals with TADF-RTP motifs.Chemical science · 2026Article
- Cryogenically Flexible Phosphorescent Organic Crystals that Transmit Self-Sustained Persistent Luminescence with Spatiotemporal Control.Journal of the American Chemical Society · 2025Article
- Surface coating induced room-temperature phosphorescence in flexible organic single crystals.Chemical science · 2024Article
- Crystal property engineering using molecular-supramolecular equivalence: mechanical property alteration in hydrogen bonded systems.Chemical science · 2024Article
- Mechanoresponsive Flexible Crystals.JACS Au · 2024Review
- Regulation Strategies of Dynamic Organic Room-Temperature Phosphorescence Materials.Chem & bio engineering · 2024Review
- Synthesis and luminescence properties of substituted benzils.Communications chemistry · 2023Article
- An atomistic mechanism for elasto-plastic bending in molecular crystals.Chemical science · 2023Article
- Plastic bending in a semiconducting coordination polymer crystal enabled by delamination.Nature communications · 2022Article
- Deformation-induced phosphorescence shift in a 2D elastically flexible organic single crystal: role of chalcogen-centered weak interactions.Chemical science · 2022Article
- Fluorescence-based thermal sensing with elastic organic crystals.Nature communications · 2022Article
- Flexible organic crystals. Understanding the tractable co-existence of elastic and plastic bending.Chemical science · 2022Article
- Hot-exciton harvestingChemical science · 2022Article
- Color-tunable persistent luminescence in 1D zinc-organic halide microcrystals for single-component white light and temperature-gating optical waveguides.Chemical science · 2022Article
- Two-Dimensional Anisotropic Flexibility of Mechanically Responsive Crystalline Cadmium(II) Coordination Polymers.Chemistry of materials : a publication of the American Chemical Society · 2022Article
- Quantifiable stretching-induced fluorescence shifts of an elastically bendable and plastically twistable organic crystal.Chemical science · 2021Article
- Mechanically compliant single crystals of a stable organic radical.Chemical science · 2021Article
- Mechanically robust amino acid crystals as fiber-optic transducers and wide bandpass filters for optical communication in the near-infrared.Nature communications · 2021Article
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Authors and funding
6 authors.
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Abstract
Recently, the study of flexible (elastically bendable and plastically bendable) organic single crystals has become a hot research field in crystal engineering. In general, crystal elasticity and plasticity are incompatible with each other. Different from the applications of fluorescent crystals, the applications of room-temperature phosphorescence (RTP) materials generally ignore the crystallographic nature of large single crystals. Herein, we creatively combine elasticity and plasticity based on one RTP crystal 4,4'-dibromobenzil DBBZL. The in-depth study of the irreversible transformation between elastic bending and plastic bending provided important insights into the mechanism of both elastically bendable crystals and plastically bendable crystals in crystal engineering. The DBBZL crystal exhibits elastic bending (reversible) under external stress, whereas it shows plastic bending (irreversible) after excessive bending. Notably, the first phosphorescent optical waveguides of large single RTP crystals are realized not only in straight state, but also in elastic bent state and plastic bent state.
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