Evidence map›Paper›PMID 30713630›Full record

ArticleChemical science2019

Manganese(ii) phosphate nanosheet assembly with native out-of-plane Mn centres for electrocatalytic water oxidation.

Hongfei Liu, Xueqing Gao, Xiaolong Yao, Mingxing Chen, Guojun Zhou, Jing Qi, Xueli Zhao, Weichao Wang, Wei Zhang, Rui Cao

Open access · diamondAbstract read
PubMed Full text at PMC Publisher
In one paragraph

Article in Chemical science, 2019. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 2 papers.

0numbers the graph read from it
0cells of the map it votes in
2citing papers in PubMed
1.6field-weighted citation impact, top 17% of its field
1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

The trial behind it

Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.

Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.

3 · Its place in the literature

Who cites it

2 citing papers in PubMed, 54 citations in OpenAlex.

  1. Article
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4 · The record

Corrections and comments

PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.

5 · Who and what money

Authors and funding

10 authors at 3 institutions in 1 country.

Hongfei LiuKey Laboratory of Applied Surface and Colloid Chemistry , Ministry of Education , School of Chemistry and Chemical Engineering , Shaanxi Normal University , Xi'an 710119 , China . Email: zw@snnu.edu.cn ; Email: ruicao@ruc.edu.cn.
Xueqing GaoKey Laboratory of Applied Surface and Colloid Chemistry , Ministry of Education , School of Chemistry and Chemical Engineering , Shaanxi Normal University , Xi'an 710119 , China . Email: zw@snnu.edu.cn ; Email: ruicao@ruc.edu.cn.
Xiaolong YaoDepartment of Electronics , Nankai University , Tianjin 300071 , China . Email: weichaowang@nankai.edu.cn.
Mingxing ChenDepartment of Chemistry , Renmin University of China , Beijing 100872 , China.
Guojun ZhouKey Laboratory of Applied Surface and Colloid Chemistry , Ministry of Education , School of Chemistry and Chemical Engineering , Shaanxi Normal University , Xi'an 710119 , China . Email: zw@snnu.edu.cn ; Email: ruicao@ruc.edu.cn.
Jing QiKey Laboratory of Applied Surface and Colloid Chemistry , Ministry of Education , School of Chemistry and Chemical Engineering , Shaanxi Normal University , Xi'an 710119 , China . Email: zw@snnu.edu.cn ; Email: ruicao@ruc.edu.cn.
Xueli ZhaoKey Laboratory of Applied Surface and Colloid Chemistry , Ministry of Education , School of Chemistry and Chemical Engineering , Shaanxi Normal University , Xi'an 710119 , China . Email: zw@snnu.edu.cn ; Email: ruicao@ruc.edu.cn.
Weichao WangDepartment of Electronics , Nankai University , Tianjin 300071 , China . Email: weichaowang@nankai.edu.cn.ORCID 0000-0001-5931-212X
Wei ZhangKey Laboratory of Applied Surface and Colloid Chemistry , Ministry of Education , School of Chemistry and Chemical Engineering , Shaanxi Normal University , Xi'an 710119 , China . Email: zw@snnu.edu.cn ; Email: ruicao@ruc.edu.cn.ORCID 0000-0002-6063-9637
Rui CaoKey Laboratory of Applied Surface and Colloid Chemistry , Ministry of Education , School of Chemistry and Chemical Engineering , Shaanxi Normal University , Xi'an 710119 , China . Email: zw@snnu.edu.cn ; Email: ruicao@ruc.edu.cn.ORCID 0000-0002-1821-9583
China XD Group (China) · CNNankai University · CNRenmin University of China · CN

Funding

No grant is acknowledged in the PubMed record.

6 · The paper itself

Abstract

Nature selects Mn-clusters as catalysts for water oxidation, which is a significant reaction in photosynthesis. Thus, it is of critical importance to develop Mn-based superstructures and study their catalytic details for water-splitting-based renewable energy research. Herein, we report a manganese(ii) phosphate nanosheet assembly with asymmetric out-of-plane Mn centers from the transformation of amine-intercalated nanoplates for efficient electrocatalytic water oxidation in neutral aqueous solutions. From structural and computational studies, it is found that the native out-of-plane Mn centers with terminal water ligands are accessible and preferential oxidation sites to form active intermediates for water oxidation. In addition, the asymmetry can stabilize the key Mn

Identifiers

PMID30713630
PMCPMC6333235
OpenAlexW2894043135

What OpenQuestion holds

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Registered trials

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Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.