ArticleJournal of the American Chemical Society2019
Enantioselective Synthesis of Azamerone.
Article in Journal of the American Chemical Society, 2019. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 7 papers.
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Who cites it
7 citing papers in PubMed.
- Conformationally Driven Dual Fluorescence Properties of Higher Heteroacenes With Periodically Incorporated Boron Atoms.Angewandte Chemie (International ed. in English) · 2026Article
- Biomimetic chlorine-induced polyene cyclizations harnessing hypervalent chloroiodane-HFIP assemblies.Chemical science · 2023Article
- Orthogonal Catalysis for an Enantioselective Domino Inverse-Electron Demand Diels-Alder/Substitution Reaction.Chemistry (Weinheim an der Bergstrasse, Germany) · 2022Article
- A Diazo-Hooker Reaction, Inspired by the Biosynthesis of Azamerone.Organic letters · 2022Article
- Meroterpenoid natural products from Streptomyces bacteria - the evolution of chemoenzymatic syntheses.Natural product reports · 2020Review
- Discoveries and Challenges en Route to Swinhoeisterol A.Chemistry (Weinheim an der Bergstrasse, Germany) · 2020Article
- 3-Bromotetrazine: labelling of macromoleculesChemical science · 2020Article
Corrections and comments
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Authors and funding
3 authors.
Funding
Abstract
A concise and selective synthesis of the dichlorinated meroterpenoid azamerone is described. The paucity of tactics for the synthesis of natural-product-relevant chiral organochlorides motivated the development of unique strategies for accessing these motifs in enantioenriched forms. The route features a novel enantioselective chloroetherification reaction, a Pd-catalyzed cross-coupling between a quinone diazide and a boronic hemiester, and a late-stage tetrazine [4+2]-cycloaddition/oxidation cascade.
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Registered trials
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