ArticleEnvironmental science. Processes & impacts2019
Surface characterization and chemical speciation of adsorbed iron(iii) on oxidized carbon nanoparticles.
Article in Environmental science. Processes & impacts, 2019. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 3 papers.
What it found
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The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.
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Who cites it
3 citing papers in PubMed, 5 citations in OpenAlex.
- Multimodal X-ray nano-spectromicroscopy analysis of chemically heterogeneous systems.Metallomics : integrated biometal science · 2022Article
- Development of a Job-Exposure Matrix for Ultrafine Particle Exposure: The MatPUF JEM.Annals of work exposures and health · 2021Review
- Iron Speciation in Particulate Matter (PMAtmospheric environment (Oxford, England : 1994) · 2021Article
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Authors and funding
4 authors at 2 institutions in 1 country.
Funding
Abstract
Carbonaceous nanomaterials represent a significant portion of ultra-fine airborne particulate matter, and iron is the most abundant transition metal in air particles. Owing to their high surface area and atmospheric oxidation, carbon nanoparticles (CNP) are enriched with surface carbonyl functional groups and act as a host for metals and small molecules. Using a synthetic model, concentration-dependent changes in the chemical speciation of iron adsorbed on oxidized carbon surfaces were investigated by a combination of X-ray and electron microscopic and spectroscopic methods. Carbon K-edge absorption spectra demonstrated that the CNP surface was enriched with carboxylic acid groups after chemical oxidation but that microporosity was unchanged. Oxidized CNP showed a high affinity for sorption of Fe(iii) from solution (75-95% uptake) and spectroscopic measurements confirmed a 3+ oxidation state of Fe on CNP irrespective of surface loading. The bonding of adsorbed Fe(iii) at variable loadings was determined by iron K-edge X-ray absorption spectroscopy. At low loadings (3 and 10 μmol Fe m-2 CNP), mononuclear Fe was octahedrally coordinated to oxygen atoms of carboxylate groups. As Fe surface coverage increased (21 and 31 μmol Fe m-2 CNP), Fe-Fe backscatters were observed at interatomic distances indicating iron (oxy)hydroxide particle formation on CNP. Electron-donating surface carboxylate groups on CNP coordinated and stabilized mononuclear Fe(iii). Saturation of high-affinity sites may have promoted hydroxide particle nucleation at higher loading, demonstrating that the chemical form of reactive metal ions may change with surface concentration and degree of CNP surface oxidation. Model systems such as those discussed here, with controlled surface properties and known chemical speciation of adsorbed metals, are needed to establish structure-activity models for toxicity assessments of environmentally relevant nanoparticles.
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Registered trials
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