ArticleNano letters2019
Structure-Activity Relationships of Hierarchical Three-Dimensional Electrodes with Photosystem II for Semiartificial Photosynthesis.
Article in Nano letters, 2019. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 25 papers.
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Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.
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Who cites it
25 citing papers in PubMed.
- Photosystem-Based Biophotoelectrodes for Solar Energy Conversion.Chemical reviews · 2026Article
- To Biotic or Abiotic: Biohybrid Systems for Artificial Photosynthesis.Chemical reviews · 2026Review
- Semiartificial COChemical reviews · 2026Review
- Living Photoanodes for Solar-Driven Water Oxidation.Chemical reviews · 2026Review
- Bio-hybrid photoelectrochemical catalysis for solar fuels and chemicals conversion.Nature communications · 2025Review
- Semiartificial Photoelectrochemistry for COJournal of the American Chemical Society · 2025Article
- Photocurrent Generation by Plant Light-Harvesting Complexes is Enhanced by Lipid-Linked Chromophores in a Self-Assembled Lipid Membrane.The journal of physical chemistry. B · 2025Article
- Operando film-electrochemical EPR spectroscopy tracks radical intermediates in surface-immobilized catalysts.Nature chemistry · 2024Article
- Thermophilic cyanobacteria-exciting, yet challenging biotechnological chassis.Applied microbiology and biotechnology · 2024Review
- Connecting Biological and Synthetic Approaches for Electrocatalytic COAngewandte Chemie (International ed. in English) · 2024Review
- Closing the green gap of photosystem I with synthetic fluorophores for enhanced photocurrent generation in photobiocathodes.Chemical science · 2023Article
- Facile fabrication of hierarchically nanostructured gold electrode for bio-electrochemical applications.Journal of electroanalytical chemistry (Lausanne, Switzerland) · 2022Article
- Stabilisierung von Elektronentransferwegen erlaubt Stabilität von Biohybrid-Photoelektroden über Jahre.Angewandte Chemie (Weinheim an der Bergstrasse, Germany) · 2022Article
- Sustaining Electron Transfer Pathways Extends Biohybrid Photoelectrode Stability to Years.Angewandte Chemie (International ed. in English) · 2022Article
- Fast CONature chemistry · 2022Article
- Graphene oxide decorated with gold enables efficient biophotovolatic cells incorporating photosystem I.RSC advances · 2022Article
- Understanding the local chemical environment of bioelectrocatalysis.Proceedings of the National Academy of Sciences of the United States of America · 2022Article
- The Interaction of Water-Soluble Nitroxide Radicals with Photosystem II.Applied magnetic resonance · 2022Article
- Photosystem II-based biomimetic assembly for enhanced photosynthesis.National science review · 2021Article
- Photovoltage generation by photosystem II core complexes immobilized onto a Millipore filter on an indium tin oxide electrode.Journal of bioenergetics and biomembranes · 2020Article
Corrections and comments
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Authors and funding
6 authors.
Funding
Abstract
Semiartificial photosynthesis integrates photosynthetic enzymes with artificial electronics, which is an emerging approach to reroute the natural photoelectrogenetic pathways for sustainable fuel and chemical synthesis. However, the reduced catalytic activity of enzymes in bioelectrodes limits the overall performance and further applications in fuel production. Here, we show new insights into factors that affect the photoelectrogenesis in a model system consisting of photosystem II and three-dimensional indium tin oxide and graphene electrodes. Confocal fluorescence microscopy and in situ surface-sensitive infrared spectroscopy are employed to probe the enzyme distribution and penetration within electrode scaffolds of different structures, which is further correlated with protein film-photoelectrochemistry to establish relationships between the electrode architecture and enzyme activity. We find that the hierarchical structure of electrodes mainly influences the protein loading but not the enzyme activity. Photoactivity is more limited by light intensity and electronic communication at the biointerface. This study provides guidelines for maximizing the performance of semiartificial photosynthesis and also presents a set of methodologies to probe the photoactive biofilms in three-dimensional electrodes.
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Registered trials
Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.