Evidence map›Paper›PMID 30678094›Full record

ReviewMembranes2019

Perfluoropolymer/Molecular Sieve Mixed-Matrix Membranes.

Gianni Golemme, Anna Santaniello

Open access · goldAbstract readReview
In one paragraph

Review in Membranes, 2019. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 2 papers.

0numbers the graph read from it
0cells of the map it votes in
2citing papers in PubMed
0.9field-weighted citation impact, top 29% of its field
1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

The trial behind it

Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.

Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.

3 · Its place in the literature

Who cites it

2 citing papers in PubMed, 11 citations in OpenAlex.

  1. Article
  2. Article
4 · The record

Corrections and comments

PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.

5 · Who and what money

Authors and funding

2 authors at 1 institution in 1 country.

Gianni GolemmeDepartment of Environmental and Chemical Engineering, University of Calabria, Via P. Bucci 45 A, 87036 Rende, Italy. giovanni.golemme@unical.it.ORCID 0000-0001-5675-4416
Anna SantanielloPhysics Department, University of Calabria, Via P. Bucci 22 C, 87036 Rende, Italy. anna.santaniello@fis.unical.it.
University of Calabria · IT

Funding

Ministero dell'Istruzione, dell'Università e della Ricerca ARS01_01259
6 · The paper itself

Abstract

Despite the outstanding chemical, thermal and transport properties of amorphous and glassy perfluorinated polymers, only few works exist on the preparation and transport properties of perfluoropolymer/molecular sieves mixed-matrix membranes (MMMs), probably because of their poor compatibility. In this review, the compatibilization of ceramic molecular sieves with perfluorinated matrices is considered first, examining the effect of the surface treatment on the gas transport properties of the filler. Then the preparation of the defect-free hybrid membranes and their gas separation capabilities are described. Finally, recent modelling of the gas transport properties of the perfluoropolymer MMMs is reviewed. The systematic use of molecular sieves of different size and shape, either permeable or impermeable, and the calculation of the bulk transport properties of the molecular sieves-i.e., the unrestricted diffusion and permeability-allow to understand the nature of the physical phenomena at work in the MMMs, that is the larger the perfluoropolymer fractional free volume at the interface, and restricted diffusion at the molecular sieves. This knowledge led to the formulation of a new four-phase approach for the modelling of gas transport. The four-phase approach was implemented in the frame of the Maxwell model and also for the finite element simulation. The four-phase approach is a convenient representation of the transport in MMMs when more than one single interfacial effect is present.

Indexed as

barriers to mass transportfinite element modelling of transportfour phases Maxwell modelfractional free volumegas separationglassy amorphous perfluoropolymersinterfacial compatibilizationmixed matrix membranesrestricted diffusionzeolitic molecular sieves

Identifiers

PMID30678094
PMCPMC6410318
OpenAlexW2912880095

What OpenQuestion holds

Textmetadata
LicenceCC BY
Read underepoch 390

Registered trials

None linked

Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.