ArticleNature communications2019
Tuning and mechanistic insights of metal chalcogenide molecular catalysts for the hydrogen-evolution reaction.
Article in Nature communications, 2019. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 10 papers.
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Who cites it
10 citing papers in PubMed.
- Atomically Precise Cluster Cocatalysts: Missing Link toward Heterogenized Photocatalytic Systems.ACS nano · 2026Review
- Assessing the Role of Composition and Size Effects in the Hydrogen Evolution Reaction on NiACS omega · 2025Article
- A thiomolybdate cluster for visible-light-driven hydrogen evolution: comparison of homogeneous and heterogeneous approaches.Sustainable energy & fuels · 2024Article
- Thiomolybdate Clusters: From Homogeneous Catalysis to Heterogenization and Active Sites.Advanced materials (Deerfield Beach, Fla.) · 2024Review
- Temperature-Dependent Structural and Electrical Properties of Metal-Organic CVD MoSNanomaterials (Basel, Switzerland) · 2023Article
- Surface Anchoring and Active Sites of [MoACS catalysis · 2022Article
- Article
- Promoting electrocatalytic overall water splitting by sulfur incorporation into CoFe-(oxy)hydroxide.Nanoscale advances · 2021Article
- Devisable POM/Ni Foam Composite: Precisely Control Synthesis toward Enhanced Hydrogen Evolution Reaction at High pH.Chemistry (Weinheim an der Bergstrasse, Germany) · 2019Article
- The rapid electrochemical activation of MoTeNature communications · 2019Article
Corrections and comments
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Authors and funding
7 authors.
Funding
No grant is acknowledged in the PubMed record.
Abstract
The production of hydrogen through water splitting using earth-abundant metal catalysts is a promising pathway for converting solar energy into chemical fuels. However, existing approaches for fine stoichiometric control, structural and catalytic modification of materials by appropriate choice of earth abundant elements are either limited or challenging. Here we explore the tuning of redox active immobilised molecular metal-chalcoxide electrocatalysts by controlling the chalcogen or metal stoichiometry and explore critical aspects of the hydrogen evolution reaction (HER). Linear sweep voltammetry (LSV) shows that stoichiometric and structural control leads to the evolution of hydrogen at low overpotential with no catalyst degradation over 1000 cycles. Density functional calculations reveal the effect of the electronic and structural features and confer plausibility to the existence of a unimolecular mechanism in the HER process based on the tested hypotheses. We anticipate these findings to be a starting point for further exploration of molecular catalytic systems.
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Registered trials
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