ArticleLangmuir : the ACS journal of surfaces and colloids2019
Mechanical Characterization of Hierarchical Structured Porous Silica by in Situ Dilatometry Measurements during Gas Adsorption.
Article in Langmuir : the ACS journal of surfaces and colloids, 2019. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 3 papers.
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3 citing papers in PubMed.
- Phase Transformations in MOFs Induced by Adsorbate Exchange.Langmuir : the ACS journal of surfaces and colloids · 2025Article
- Drying of Hierarchically Organized Porous Silica Monoliths-Comparison of Evaporative and Supercritical Drying.Gels (Basel, Switzerland) · 2023Article
- In Situ Small-Angle Neutron Scattering Investigation of Adsorption-Induced Deformation in Silica with Hierarchical Porosity.Langmuir : the ACS journal of surfaces and colloids · 2019Article
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Authors and funding
8 authors.
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Abstract
Mechanical properties of hierarchically structured nanoporous materials are determined by the solid phase stiffness and the pore network morphology. We analyze the mechanical stiffness of hierarchically structured silica monoliths synthesized via a sol-gel process, which possess a macroporous scaffold built of interconnected struts with hexagonally ordered cylindrical mesopores. We consider samples with and without microporosity within the mesopore walls and analyze them on the macroscopic level as well as on the microscopic level of the mesopores. Untreated as-prepared samples still containing some organic components and the respective calcined and sintered counterparts of varying microporosity are investigated. To determine Young's moduli on the level of the macroscopic monoliths, we apply ultrasonic run time measurements, while Young's moduli of the mesopore walls are obtained by analysis of the in situ strain isotherms during N
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