ArticleAngewandte Chemie (International ed. in English)2019
Cofactor Controlled Encapsulation of a Rhodium Hydroformylation Catalyst.
Article in Angewandte Chemie (International ed. in English), 2019. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 12 papers.
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Who cites it
12 citing papers in PubMed.
- Design Rules for Sb and Bi Porphyrin Capsules: Para-Substitution Effects and Pnictogen Bond Conformational Control.Inorganic chemistry · 2026Article
- Exo-templating via pseudorotaxane formation reduces pathway complexity in the multicomponent self-assembly of MNature chemistry · 2025Article
- Chemo-, regio- and enantioselective hydroformylation of trisubstituted cyclopropenes: access to chiral quaternary cyclopropanes.Nature communications · 2024Article
- Structural and dimensional control of porphyrin capsules using Group 15 tris(3-pyridyl) linkers.Chemical science · 2023Article
- Adaptive coordination assemblies based on a flexible tetraazacyclododecane ligand for promoting carbon dioxide fixation.Chemical science · 2022Article
- Allosteric Guest Binding in Chiral Zirconium(IV) Double Decker Porphyrin Cages.European journal of organic chemistry · 2021Article
- Double Porphyrin Cage Compounds.European journal of organic chemistry · 2020Article
- Topological prediction of palladium coordination cages.Chemical science · 2020Article
- Article
- Asymmetric Hydroformylation Using a Rhodium Catalyst Encapsulated in a Chiral Capsule.Chemistry, an Asian journal · 2020Article
- Effector responsive hydroformylation catalysis.Chemical science · 2019Article
- Cofactor Controlled Encapsulation of a Rhodium Hydroformylation Catalyst.Angewandte Chemie (International ed. in English) · 2019Article
Corrections and comments
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Authors and funding
3 authors.
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No grant is acknowledged in the PubMed record.
Abstract
Supramolecular approaches in transition-metal catalysis, including catalyst encapsulation, have attracted considerable attention. Compared to enzymes, supramolecular catalysts in general are less complex. Enzyme activity is often controlled by the use of smaller cofactor molecules, which is important in order to control reactivity in complex mixtures of molecules. Interested in increasing complexity and allowing control over supramolecular catalyst formation in response to external stimuli, we designed a catalytic system that only forms an efficient supramolecular complex when a small cofactor molecule is added to the solution. This in turn affects both the activity and selectivity when applied in a hydroformylation reaction. This contribution shows that catalyst encapsulation can be controlled by the addition of a cofactor, which affects crucial catalyst properties.
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Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.