ArticleFrontiers in chemistry2018
Confinement Effects in Catalysis Using Well-Defined Materials and Cages.
Article in Frontiers in chemistry, 2018. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 47 papers.
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Who cites it
47 citing papers in PubMed.
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- Confinement Catalysis Enables Macrocyclization at Up to 0.6 M: Selective Formation of Mono- and Dimeric Glycosidic Macrocycles.Journal of the American Chemical Society · 2026Article
- Carbonaceous supports for Schiff base metal complexes: Strategies for enhanced catalytic efficiency.iScience · 2026Review
- Oxidative Ring-Opening of Dimethylfuran in Zeolitic Imidazolate Frameworks through Computational Design.The journal of physical chemistry. C, Nanomaterials and interfaces · 2026Article
- Photo-Driven COChemSusChem · 2026Article
- Surveying the Homogeneity of a Molecular Electrocatalyst Embedded in a Metal-Organic Framework Using Operando Characterization.ChemSusChem · 2025Article
- An Artificial Metal-Free Peroxidase Designed Using a Ferritin Cage for Bioinspired Catalysis.Angewandte Chemie (International ed. in English) · 2025Article
- Cis-Chelating Diphosphanes for Intracavity Nickel(II)-Catalyzed Ethylene Oligomerization.Chemistry (Weinheim an der Bergstrasse, Germany) · 2025Article
- The Role of Metal-Organic Framework Induced Confinement Effects on Molecular Electrocatalysts Relevant to the Energy Transition.ChemSusChem · 2025Review
- Scalable Production and Multifunctional Coating of Gold Nanostars for Catalytic Applications.Nanomaterials (Basel, Switzerland) · 2025Article
- Computational Study of Alkyne-Acid Cycloisomerization in Gold-Functionalized Resorcinarene Cavitand.Chemistry (Weinheim an der Bergstrasse, Germany) · 2025Article
- Nanoconfinement Effects in Electrocatalysis and Photocatalysis.Small (Weinheim an der Bergstrasse, Germany) · 2025Review
- Influence of Ionic Liquid Film Thickness and Flow Rate on Macrocyclization Efficiency and Selectivity in Supported Ionic Liquid-Liquid Phase Catalysis.Chemistry (Weinheim an der Bergstrasse, Germany) · 2025Article
- Reactivity Inside Molecular Flasks: Acceleration Modes and Types of Selectivity Obtainable.Angewandte Chemie (International ed. in English) · 2024Review
- Hydrogenation Versus Hydrosilylation: The Substantial Impact of a Palladium Capsule on the Catalytic Outcome.Molecules (Basel, Switzerland) · 2024Article
- Window[1]resorcin[3]arenes: A Novel Macrocycle Able to Self-Assemble to a Catalytically Active Hexameric Cage.JACS Au · 2024Article
- Biomimetic tail-to-head terpene cyclizations using the resorcin[4]arene capsule catalyst.Nature protocols · 2024Review
- Reactant enrichment in hollow void of Pt NPs@MnOx nanoreactors for boosting hydrogenation performance.National science review · 2023Article
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Authors and funding
4 authors.
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Abstract
This review focuses on the effects that confinement of molecular and heterogeneous catalysts with well-defined structure has on the selectivity and activity of these systems. A general introduction about catalysis and how the working principles of enzymes can be used as a source of inspiration for the preparation of catalysts with enhanced performance is provided. Subsequently, relevant studies demonstrate the importance of second coordination sphere effects in a broad sense (in homogeneous and heterogeneous catalysis). Firstly, we discuss examples involving zeolites, MOFs and COFs as heterogeneous catalysts with well-defined structures where confinement influences catalytic performance. Then, specific cases of homogeneous catalysts where non-covalent interactions determine the selectivity and activity are treated in detail. This includes examples based on cyclodextrins, calix[n]arenes, cucurbit[n]urils, and self-assembled container molecules. Throughout the review, the impact of confined spaces is emphasized and put into context, in order to get a better understanding of the effects of confinement on catalyst performance. In addition, this analysis intends to showcase the similarities between homogeneous and heterogeneous catalysts, which may aid the development of novel strategies.
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