ArticleJournal of the American Chemical Society2019
Rhodium-Catalyzed Asymmetric Hydroamination of Allyl Amines.
Article in Journal of the American Chemical Society, 2019. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 15 papers.
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Who cites it
15 citing papers in PubMed.
- Iridium-catalysed hydroamination of internal homoallylic amines.Chemical communications (Cambridge, England) · 2024Article
- NiH-catalyzed C-N bond formation: insights and advancements in hydroamination of unsaturated hydrocarbons.Chemical science · 2024Review
- Scope and Mechanistic Probe into Asymmetric Synthesis of α-Trisubstituted-α-Tertiary Amines by Rhodium Catalysis.Journal of the American Chemical Society · 2023Article
- Progression of Hydroamination Catalyzed by Late Transition-Metal Complexes from Activated to Unactivated Alkenes.Accounts of chemical research · 2023Article
- Synthesis of Unsymmetrical Vicinal Diamines via Directed Hydroamination.Organic letters · 2022Article
- Rhodium-/Iridium-Catalyzed Hydroamination for the Synthesis of 1,2-, 1,3-, or 1,4-Diamines.ACS catalysis · 2022Article
- Article
- A Diastereodivergent and Enantioselective Approach toJournal of the American Chemical Society · 2021Article
- Design, scope and mechanism of highly active and selective chiral NHC-iridium catalysts for the intramolecular hydroamination of a variety of unactivated aminoalkenes.Chemical science · 2021Article
- Ruthenium-Catalyzed Hydroamination of Unactivated Terminal Alkenes with Stoichiometric Amounts of Alkene and an Ammonia Surrogate by Sequential Oxidation and Reduction.Journal of the American Chemical Society · 2021Article
- Article
- Intermolecular Hydroaminoalkylation of Propadiene.Chemistry (Weinheim an der Bergstrasse, Germany) · 2020Article
- Ligand-promoted cobalt-catalyzed radical hydroamination of alkenes.Nature communications · 2020Article
- A minireview of hydroamination catalysis: alkene and alkyne substrate selective, metal complex design.BMC chemistry · 2019Review
- Regio- and Enantioselective Synthesis of 1,2-Diamine Derivatives by Copper-Catalyzed Hydroamination.Organic letters · 2019Article
Corrections and comments
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Authors and funding
6 authors.
Funding
Abstract
A Rh-catalyzed enantioselective hydroamination of allylamines using a chiral BIPHEP-type ligand is reported. Enantioenriched 1,2-diamines are formed in good yields and with excellent enantioselectivities. A diverse array of nucleophiles and amine directing groups are demonstrated, including deprotectable motifs. Finally, the methodology was demonstrated toward the rapid synthesis of 2-methyl-moclobemide.
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Registered trials
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