Selective Carbanion-Pyridine Coordination of a Reactive P,N Ligand to Rh

Marc Devillard, Andreas Ehlers, Maxime A Siegler, Jarl Ivar van der Vlugt

Open access · hybridAbstract read

In one paragraph

Article in Chemistry (Weinheim an der Bergstrasse, Germany), 2019. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 1 paper.

0numbers the graph read from it

0cells of the map it votes in

1citing papers in PubMed

0.9field-weighted citation impact, top 32% of its field

1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

The trial behind it

Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.

Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.

3 · Its place in the literature

Who cites it

1 citing paper in PubMed, 10 citations in OpenAlex.

Selective Carbanion-Pyridine Coordination of a Reactive P,N Ligand to RhChemistry (Weinheim an der Bergstrasse, Germany) · 2019
Article

4 · The record

Corrections and comments

PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.

5 · Who and what money

Authors and funding

4 authors at 3 institutions in 3 countries.

Marc Devillardvan 't Hoff Institute for Molecular Sciences, University of Amsterdam, Science Park 904, 1098 XH, Amsterdam, The Netherlands.

Andreas Ehlersvan 't Hoff Institute for Molecular Sciences, University of Amsterdam, Science Park 904, 1098 XH, Amsterdam, The Netherlands.

Maxime A SieglerDepartment of Chemistry, Johns Hopkins University, 3400 N Charles Street, Baltimore, MD, 21218, USA.

Jarl Ivar van der Vlugtvan 't Hoff Institute for Molecular Sciences, University of Amsterdam, Science Park 904, 1098 XH, Amsterdam, The Netherlands.ORCID http://orcid.org/0000-0003-0665-9239

University of Amsterdam · NLJohns Hopkins University · USUniversity of Johannesburg · ZA

Funding

FP7 Ideas: European Research Council 279097

6 · The paper itself

Abstract

Ligands with reactive carbon sites in the periphery of a metal center have emerged as a powerful approach for metal-ligand bond activation. These reactive carbon sites are commonly generated by deprotonation strategies. Carbon-silicon bond cleavage is a potential alternative to access such constructs. Herein, the monodesilylation of bis-silyl-substituted P,N scaffold PN

Indexed as

C−H activationcoordination modesmetallacyclesN,P ligandsrhodium

Identifiers

PMID30600857

DOI10.1002/chem.201805504

PMCPMC6519283

OpenAlexW2908180645

What OpenQuestion holds

Textmetadata

LicenceCC BY-NC-ND

Read underepoch 390

Registered trials

None linked

Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.