ArticleJournal of the American Chemical Society2019
Concise Total Synthesis of Herqulines B and C.
Article in Journal of the American Chemical Society, 2019. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 11 papers.
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Who cites it
11 citing papers in PubMed.
- Fragment-Guided Genome Mining of Octacyclic Cyclophane Alkaloids from Fungi.Journal of the American Chemical Society · 2024Article
- Photoredox catalysis harvesting multiple photon or electrochemical energies.Beilstein journal of organic chemistry · 2023Review
- Catalytic Oxidative Coupling of Phenols and Related Compounds.ACS catalysis · 2022Article
- Electrochemical Activation of Diverse Conventional Photoredox Catalysts Induces Potent Photoreductant Activity*.Angewandte Chemie (International ed. in English) · 2021Article
- Ideality in Context: Motivations for Total Synthesis.Accounts of chemical research · 2021Article
- Oxidative Photocatalytic Homo- and Cross-Coupling of Phenols: Nonenzymatic, Catalytic Method for Coupling Tyrosine.ACS catalysis · 2020Article
- Late-stage and strain-accelerated oxidation enabled synthesis of haouamine A.Chemical science · 2020Article
- Potent Reductants via Electron-Primed Photoredox Catalysis: Unlocking Aryl Chlorides for Radical Coupling.Journal of the American Chemical Society · 2020Article
- Total synthesis reveals atypical atropisomerism in a small-molecule natural product, tryptorubin A.Science (New York, N.Y.) · 2020Article
- Substrate-Assisted Hydroxylation andACS catalysis · 2020Article
- Molecular Transformer: A Model for Uncertainty-Calibrated Chemical Reaction Prediction.ACS central science · 2019Article
Corrections and comments
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Authors and funding
3 authors.
Funding
Abstract
A simple total synthesis of herqulines B and C is reported, modeled on the reductive biosynthesis reported previously by other researchers. Commencing from tyrosine, these alkaloids were fashioned through a dimerization, macrocyclization, and four consecutive reductions. Emerging from these studies are strategic insights on the synthesis of these strained alkaloids, as well as mild conditions for the exhaustive reduction of diketopiperizines.
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Registered trials
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