ArticleThe European physical journal. E, Soft matter2018
Interfacial transport with mobile surface charges and consequences for ionic transport in carbon nanotubes.
Article in The European physical journal. E, Soft matter, 2018. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 7 papers.
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Who cites it
7 citing papers in PubMed.
- Ionic species programmable synaptic plasticity in multimodal nanofluidic devices.National science review · 2026Article
- Coupling between ion transport and electronic properties in individual carbon nanotubes.Science advances · 2025Article
- Surface diffusion enhanced ion transport through two-dimensional nanochannels.Science advances · 2023Article
- Enhanced osmotic transport in individual double-walled carbon nanotube.Nature communications · 2023Article
- Enhanced nanofluidic transport in activated carbon nanoconduits.Nature materials · 2022Article
- Nanofluidic osmotic power generators - advanced nanoporous membranes and nanochannels for blue energy harvesting.Chemical science · 2021Review
- Anomalous interfacial dynamics of single proton charges in binary aqueous solutions.Science advances · 2021Article
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Authors and funding
2 authors.
Funding
No grant is acknowledged in the PubMed record.
Abstract
In this paper, we explore the effect of a finite surface charge mobility on the interfacial transport: conductance, streaming currents, electro- and diffusio-osmotic flows. We first show that the surface charge mobility modifies the hydrodynamic boundary condition for the fluid, which introduces a supplementary term depending on the applied electric field. In particular, the resulting slip length is found to decrease inversely with the surface charge. We then derive expressions for the various transport mobilities, highlighting that the surface charge mobility merely moderates the amplification effect of interfacial slippage, to the noticeable exception of diffusio-osmosis and surface conductance. Our calculations, obtained within Poisson-Boltzmann framework, highlight the importance of non-linear electrostatic contributions to predict the small concentration/large charge limiting regimes for the transport mobilities. We discuss these predictions in the context of recent electrokinetic experiments with carbon nanotubes.
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Registered trials
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