ArticleJournal of the American Chemical Society2019
Cobalt-Catalyzed Electrophilic Aminations with Anthranils: An Expedient Route to Condensed Quinolines.
Article in Journal of the American Chemical Society, 2019. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 10 papers.
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Who cites it
10 citing papers in PubMed.
- A decade of progress in transition metal-catalyzed sulfoxide reductions.Molecular diversity · 2026Review
- Review
- Simple and versatile electrochemical synthesis of highly substituted 2,1-benzisoxazoles.Organic & biomolecular chemistry · 2025Article
- Theoretical Study on the Mechanism of Cobalt-Catalyzed C-O Silylation and Stannylation.ACS omega · 2023Article
- 1,4-Dithianes: attractive C2-building blocks for the synthesis of complex molecular architectures.Beilstein journal of organic chemistry · 2023Review
- Practical synthesis of 3-aryl anthranilsChemical science · 2022Article
- Modular Two-Step Access to π-Extended Naphthyridine Systems-Potent Building Blocks for Organic Electronics.Angewandte Chemie (International ed. in English) · 2022Article
- Organozinc pivalates for cobalt-catalyzed difluoroalkylarylation of alkenes.Nature communications · 2021Article
- Synthetic and medicinal perspective of quinolines as antiviral agents.European journal of medicinal chemistry · 2021Review
- Understanding metal synergy in heterodinuclear catalysts for the copolymerization of CONature chemistry · 2020Article
Corrections and comments
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Authors and funding
8 authors.
Funding
No grant is acknowledged in the PubMed record.
Abstract
The reaction of various organozinc pivalates with anthranils provides anilines derivatives, which cyclize under acidic conditions providing condensed quinolines. Using alkenylzinc pivalates, electron-rich arylzinc pivalates or heterocyclic zinc pivalates produces directly the condensed quinolines of which several structures belong to new heterocyclic scaffolds. These N-heterocycles are of particular interest for organic light emitting diodes with their high photoluminescence quantum yields and long exciton lifetimes as well as for hole-transporting materials in methylammonium lead iodide perovskites solar cells due to an optimal band alignment for holes and a large bandgap.
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Registered trials
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