ArticleAngewandte Chemie (International ed. in English)2019
Transformation of Imine Cages into Hydrocarbon Cages.
Article in Angewandte Chemie (International ed. in English), 2019. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 19 papers.
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Who cites it
19 citing papers in PubMed.
- Chiral covalent organic cages: Construction and chiral functions.Smart molecules : open access · 2025Review
- Beyond symmetric self-assembly and effective molarity: unlocking functional enzyme mimics with robust organic cages.Beilstein journal of organic chemistry · 2025Article
- Dynamic covalent synthesis.Chemical science · 2024Review
- Crystalline Nanoparticles of Water-Soluble Covalent Basket Cages (CBCs) for Encapsulation of Anticancer Drugs.Angewandte Chemie (International ed. in English) · 2023Article
- [2+3] Amide Cages by Oxidation of [2+3] Imine Cages - Revisiting Molecular Hosts for Highly Efficient Nitrate Binding.Chemistry (Weinheim an der Bergstrasse, Germany) · 2022Article
- Purely Covalent Molecular Cages and Containers for Guest Encapsulation.Chemical reviews · 2022Review
- Chiral self-sorting and guest recognition of porous aromatic cages.Nature communications · 2022Article
- Cucurbitimines - imine cages with concave walls.Organic chemistry frontiers : an international journal of organic chemistry · 2021Article
- Soluble Congeners of Prior Insoluble Shape-Persistent Imine Cages.Chemistry (Weinheim an der Bergstrasse, Germany) · 2021Article
- Porous shape-persistent rylene imine cages with tunable optoelectronic properties and delayed fluorescence.Chemical science · 2021Article
- A Giant [8+12] Boronic Ester Cage with 48 Terminal Alkene Units in the Periphery for Postsynthetic Alkene Metathesis.Chemistry (Weinheim an der Bergstrasse, Germany) · 2021Article
- Examination of the Dynamic Covalent Chemistry of [2 + 3]-Imine Cages.The Journal of organic chemistry · 2020Article
- A Robust Porous Quinoline Cage: Transformation of a [4+6] Salicylimine Cage by Povarov Cyclization.Angewandte Chemie (International ed. in English) · 2020Article
- Inducing Social Self-Sorting in Organic Cages To Tune The Shape of The Internal Cavity.Angewandte Chemie (International ed. in English) · 2020Article
- Switching porosity of stable triptycene-based cageRSC advances · 2020Article
- Singlet oxygen stimulus for switchable functional organic cages.Chemical science · 2020Article
- Different Modes of Anion Response Cause Circulatory Phase Transfer of a Coordination Cage with Controlled Directionality.Angewandte Chemie (International ed. in English) · 2019Article
- Transformation of Imine Cages into Hydrocarbon Cages.Angewandte Chemie (International ed. in English) · 2019Article
- Tuning the Solubility of Self-Assembled Fluorescent Aromatic Cages Using Functionalized Amino Acid Building Blocks.Frontiers in chemistry · 2019Article
Corrections and comments
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Authors and funding
4 authors.
Funding
Abstract
In contrast to organic cages which are formed by exploiting dynamic covalent chemistry, such as boronic ester cages, imine cages, or disulfide cages, those with a fully carbonaceous backbone are rarer. With the exception of alkyne metathesis based approaches, the vast majority of hydrocarbon cages need to be synthesized by kinetically controlled bond formation. This strategy implies a multiple step synthesis and no correction mechanism in the final macrocyclization step, both of which are responsible for low overall yields. Whereas for smaller cages the intrinsic drawbacks are not always obvious, larger cages are seldom synthesized in yields beyond a few tenths of a percent. Presented herein is a three-step method to convert imine cages into hydrocarbon cages. The method has been successfully applied to even larger structures such as derivatives of C
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