ArticleNature communications2018
Molecular Russian dolls.
Article in Nature communications, 2018. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 14 papers.
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Who cites it
14 citing papers in PubMed.
- Designing Tailored Molecular Cavities Using Calix[5]arenes as Building Blocks.Chemical record (New York, N.Y.) · 2026Article
- Hosting of [Cs(crown ether)Chemical science · 2025Article
- Rapid and facile one-step microwave synthesis of macrobicyclic cryptands.Acta crystallographica. Section E, Crystallographic communications · 2025Article
- Article
- The Story of the Little Blue Box: A Tribute to Siegfried Hünig.Angewandte Chemie (International ed. in English) · 2023Review
- A self-complementary macrocycle by a dual interaction system.Nature communications · 2022Article
- Taming Tris(bipyridine)ruthenium(II) and Its Reactions in Water by Capture/Release with Shape-Switchable Symmetry-Matched Cyclophanes.Journal of the American Chemical Society · 2022Article
- Electrostatically cooperative host-in-host of metal cluster ⊂ ionic organic cages in nanopores for enhanced catalysis.Nature communications · 2022Article
- Specific Noncovalent Association of TruncatedThe Journal of organic chemistry · 2022Article
- Electron-catalysed molecular recognition.Nature · 2022Article
- Radical-pairing-induced molecular assembly and motion.Nature reviews. Chemistry · 2021Review
- A three-shell supramolecular complex enables the symmetry-mismatched chemo- and regioselective bis-functionalization of CNature chemistry · 2021Article
- Selective synthesis and structural transformation between a molecular ring-in-ring architecture and an abnormal trefoil knot.Chemical science · 2020Article
- Tuning radical interactions in trisradical tricationic complexes by varying host-cavity sizes.Chemical science · 2020Article
Corrections and comments
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Authors and funding
15 authors.
Funding
No grant is acknowledged in the PubMed record.
Abstract
The host-guest recognition between two macrocycles to form hierarchical non-intertwined ring-in-ring assemblies remains an interesting and challenging target in noncovalent synthesis. Herein, we report the design and characterization of a box-in-box assembly on the basis of host-guest radical-pairing interactions between two rigid diradical dicationic cyclophanes. One striking feature of the box-in-box complex is its ability to host various 1,4-disubstituted benzene derivatives inside as a third component in the cavity of the smaller of the two diradical dicationic cyclophanes to produce hierarchical Russian doll like assemblies. These results highlight the utility of matching the dimensions of two different cyclophanes as an efficient approach for developing new hybrid supramolecular assemblies with radical-paired ring-in-ring complexes and smaller neutral guest molecules.
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Registered trials
Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.