ArticleChemical communications (Cambridge, England)2019
Metal-catalyzed cross-coupling chemistry with polyhedral boranes.
Article in Chemical communications (Cambridge, England), 2019. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 26 papers.
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Who cites it
26 citing papers in PubMed.
- Article
- A General Sonogashira-Type Strategy for Exopolyhedral B-C(sp) Bond Formation onOrganic letters · 2026Article
- Deprotonation-controlled copper-free Pd-catalyzed Sonogashira couplingRSC advances · 2026Article
- Stereospecific alkenylation of carboranes: copper-catalyzed access to pyridylcarboranyl alkenes.Chemical science · 2026Article
- Raising the HOMO level of the [Chemical science · 2026Article
- Iridium(III)-catalyzed remote B(9)-H alkylation of o-carboranes with nitrile template.Nature communications · 2025Article
- Vertex Engineering of the Dodecaborate-Based Broadband Membrane Carriers.Inorganic chemistry · 2025Article
- An Isolated LithiumJournal of the American Chemical Society · 2025Article
- Carboranes without Cage Carbons:Journal of the American Chemical Society · 2025Article
- A Pd-catalyzed route to carborane-fused boron heterocycles.Chemical science · 2024Article
- Palladium-Catalyzed Regioselective B(3,5)-Dialkenylation and B(4)-Alkenylation ofThe Journal of organic chemistry · 2024Article
- Selective Functionalization of CarbonylMolecules (Basel, Switzerland) · 2023Article
- Towards the Application of Purely Inorganic Icosahedral Boron Clusters in Emerging Nanomedicine.Molecules (Basel, Switzerland) · 2023Review
- Electrochemical Cage Activation of Carboranes.Angewandte Chemie (International ed. in English) · 2022Review
- Palladium-Mediated Incorporation of Carboranes into Small Molecules, Peptides, and Proteins.Journal of the American Chemical Society · 2022Article
- Carboranes as unique pharmacophores in antitumor medicinal chemistry.Molecular therapy oncolytics · 2022Review
- Ir-catalyzed enantioselective B-H alkenylation for asymmetric synthesis of chiral-at-cage o‑carboranes.Nature communications · 2021Article
- ElectrooxidativeChemical science · 2021Article
- Electrochemical B-H Nitrogenation: Access to Amino Acid and BODIPY-Labeled nido-Carboranes.Angewandte Chemie (International ed. in English) · 2021Article
- Expanding the Scope of Palladium-Catalyzed B - N Cross-Coupling Chemistry in Carboranes.Organometallics · 2020Article
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Funding
Abstract
Over the past several decades, metal-catalyzed cross-coupling has emerged as a very powerful strategy to functionalize carbon-based molecules. More recently, some of the cross-coupling methodologies have been adapted to inorganic compounds including boron-rich clusters. The development of this chemistry relies on the ability to synthesize halogenated boron-rich clusters which can serve as electrophilic cross-coupling partners with nucleophilic substrates in the presence of a metal catalyst. While the cross-coupling chemistry with boron-clusters is conceptually reminiscent of that of its hydrocarbon counterparts, several key aspects including the spheroidal bulk of clusters and the distinct nature of boron-halogen/boron-heteroatom bonds make this chemistry unique. The utility of metal-catalyzed cross-coupling can be extended to several classes of polyhedral boranes including neutral and anionic carboranes, metallaboranes, and carbon-free boranes. Importantly, cross-coupling enables a suite of boron-heteroatom (C, N, O, P, S) couplings to prepare boron cluster-based systems that can be used for ligand design, medicinal chemistry, and materials applications.
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