Evidence map›Paper›PMID 30520228›Full record

ArticleAngewandte Chemie (International ed. in English)2019

Enantiospecific Synthesis of ortho-Substituted 1,1-Diarylalkanes by a 1,2-Metalate Rearrangement/anti-S

Belén Rubial, Beatrice S L Collins, Raphael Bigler, Stefan Aichhorn, Adam Noble, Varinder K Aggarwal

Abstract read
In one paragraph

Article in Angewandte Chemie (International ed. in English), 2019. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 8 papers.

0numbers the graph read from it
0cells of the map it votes in
8citing papers in PubMed
–field-weighted citation impact
1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

The trial behind it

Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.

Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.

3 · Its place in the literature

Who cites it

8 citing papers in PubMed.

  1. Article
  2. Article
  3. Article
  4. Article
  5. Stereospecific 1,2-Migrations of Boronate Complexes Induced by Electrophiles.Angewandte Chemie (International ed. in English) · 2020
    Review
  6. Article
  7. Article
  8. Article
4 · The record

Corrections and comments

PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.

5 · Who and what money

Authors and funding

6 authors.

Belén RubialSchool of Chemistry, University of Bristol, Cantock's Close, Bristol, BS8 1TS, UK.
Beatrice S L CollinsSchool of Chemistry, University of Bristol, Cantock's Close, Bristol, BS8 1TS, UK.
Raphael BiglerSchool of Chemistry, University of Bristol, Cantock's Close, Bristol, BS8 1TS, UK.
Stefan AichhornSchool of Chemistry, University of Bristol, Cantock's Close, Bristol, BS8 1TS, UK.
Adam NobleSchool of Chemistry, University of Bristol, Cantock's Close, Bristol, BS8 1TS, UK.ORCID 0000-0001-9203-7828
Varinder K AggarwalSchool of Chemistry, University of Bristol, Cantock's Close, Bristol, BS8 1TS, UK.ORCID 0000-0003-0344-6430

Funding

PHYSICIAN SCIENTIST TRAINING GRANT IN ONCOLOGYK12CA001723 · NCI · UNIVERSITY OF TEXAS HLTH SCI CTR SAN ANT · PI TAKIMOTO, CHRIS H · 1992 to 2001
$837k
EPIDEMIOLOGY OF NONHODGKIN'S LYMPHOMAR01CA038071 · NCI · HARVARD UNIVERSITY (MEDICAL SCHOOL) · PI MACMAHON, BRIAN · 1986 to 1988
–
Austrian Science Fund J3919-N28Biotechnology and Biological Sciences Research Council BB/F011539/1Engineering and Physical Sciences Research Council EP/I038071/1Gobierno del Principado de Asturias ACA17-23H2020 European Research Council 670668Schweizerischer Nationalfonds zur Förderung der Wissenschaftlichen Forschung P2EZP2_165268
6 · The paper itself

Abstract

The one-pot sequential coupling of benzylamines, boronic esters, and aryl iodides has been investigated. In the presence of an N-activator, the boronate complex formed from an ortho-lithiated benzylamine and a boronic ester undergoes stereospecific 1,2-metalate rearrangement/anti-S

Indexed as

1,1-diarylalkaneboronic estercross-couplingone-potstereospecific

Identifiers

PMID30520228
PMCPMC6391954

What OpenQuestion holds

Textmetadata
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Read underepoch 390

Registered trials

None linked

Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.