Evidence map›Paper›PMID 30516995›Full record

ArticleJournal of the American Chemical Society2018

Metallaphotoredox-Catalyzed Cross-Electrophile C

Russell T Smith, Xiaheng Zhang, Juan A Rincón, Javier Agejas, Carlos Mateos, Mario Barberis, Susana García-Cerrada, Oscar de Frutos, David W C MacMillan

Abstract read
In one paragraph

Article in Journal of the American Chemical Society, 2018. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 67 papers.

0numbers the graph read from it
0cells of the map it votes in
67citing papers in PubMed
–field-weighted citation impact
1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

The trial behind it

Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.

Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.

3 · Its place in the literature

Who cites it

67 citing papers in PubMed.

  1. Article
  2. Article
  3. Article
  4. Review
  5. Recyclable dual Z-scheme perovskite/g-CNature communications · 2026
    Article
  6. Ring-opening decarbonylative C(spChemical science · 2026
    Article
  7. Intermolecular Cyclization of Alkyl Chains of Ketones for ConstructingJournal of the American Chemical Society · 2026
    Article
  8. Article
  9. Article
  10. Photocatalytic C(spNature communications · 2025
    Article
  11. Copper-Photoredox-Catalyzed C(spAngewandte Chemie (International ed. in English) · 2025
    Article
  12. Radical Sorting Catalysis via Bimolecular Homolytic Substitution (SJournal of the American Chemical Society · 2025
    Review
  13. Article
  14. Article
  15. Article
  16. Iron-Catalyzed Cross-Electrophile Coupling.Synlett : accounts and rapid communications in synthetic organic chemistry · 2025
    Article
  17. Palladium-Catalyzed Oxidative Allene-Allene Cross-Coupling.Journal of the American Chemical Society · 2025
    Article
  18. Review
  19. CspACS catalysis · 2024
    Article
  20. Article

7 more citing papers are in PubMed but not listed here.

4 · The record

Corrections and comments

PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.

5 · Who and what money

Authors and funding

9 authors.

Russell T SmithMerck Center for Catalysis at Princeton University , Princeton , New Jersey 08544 , United States.
Xiaheng ZhangMerck Center for Catalysis at Princeton University , Princeton , New Jersey 08544 , United States.ORCID 0000-0002-9999-1347
Juan A RincónCentro de Investigación Lilly S.A. , Avda. de la Industria 30 , Alcobendas - Madrid 28108 , Spain.
Javier AgejasCentro de Investigación Lilly S.A. , Avda. de la Industria 30 , Alcobendas - Madrid 28108 , Spain.
Carlos MateosCentro de Investigación Lilly S.A. , Avda. de la Industria 30 , Alcobendas - Madrid 28108 , Spain.ORCID 0000-0002-0189-4136
Mario BarberisCentro de Investigación Lilly S.A. , Avda. de la Industria 30 , Alcobendas - Madrid 28108 , Spain.
Susana García-CerradaCentro de Investigación Lilly S.A. , Avda. de la Industria 30 , Alcobendas - Madrid 28108 , Spain.
Oscar de FrutosCentro de Investigación Lilly S.A. , Avda. de la Industria 30 , Alcobendas - Madrid 28108 , Spain.
David W C MacMillanMerck Center for Catalysis at Princeton University , Princeton , New Jersey 08544 , United States.ORCID 0000-0001-6447-0587

Funding

Photoredox Catalysis in Organic ChemistryR01GM093213 · NIGMS · PRINCETON UNIVERSITY · PI MACMILLAN, DAVID W · 2010 to 2019
$3.0M
NIGMS NIH HHS R01 GM093213
6 · The paper itself

Abstract

A strategy for the installation of small alkyl fragments onto pharmaceutically relevant aliphatic structures has been established via metallaphotoredox catalysis. Herein, we report that tris(trimethylsilyl)silanol can be employed as an effective halogen abstraction reagent that, in combination with photoredox and nickel catalysis, allows a generic approach to C

Indexed as

AlkanesCatalysisCoordination ComplexesHydrocarbons, BrominatedIridiumLightMolecular StructureNickelTrimethylsilyl CompoundsAlkanesCoordination ComplexesHydrocarbons, BrominatedIridiumNickelTrimethylsilyl Compounds

Identifiers

PMID30516995
PMCPMC6697083

What OpenQuestion holds

Textmetadata
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Read underepoch 390

Registered trials

None linked

Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.