ArticleNature chemistry2019
Highly responsive nature of porous coordination polymer surfaces imaged by in situ atomic force microscopy.
Article in Nature chemistry, 2019. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 16 papers.
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Who cites it
16 citing papers in PubMed.
- Real-Space Molecular Resolution Imaging of Graphite-Anchored MOF Surfaces via Atomic Force Microscopy at the Liquid-Solid Interface.Small methods · 2026Article
- Cooperative Host-Guest Complexation in Densely Assembled Host Structures on Surfaces Revealed at the Single-Molecular Level.Journal of the American Chemical Society · 2026Article
- Surface Reconstruction in Hydrated Amphiphilic Block Copolymer Thin Films Probed by Fluid Cell Atomic Force Microscopy.Macromolecules · 2026Article
- Adsorption and Separation by Flexible MOFs.Advanced materials (Deerfield Beach, Fla.) · 2025Review
- Nanoscale Flexing Mechanism of a Metal-Organic Framework Determined by Atomic Force Microscopy.Journal of the American Chemical Society · 2025Article
- Molecular-level insights into the supramolecular gelation mechanism of urea derivative.Nature communications · 2025Article
- Generalised analytical method unravels framework-dependent kinetics of adsorption-induced structural transition in flexible metal-organic frameworks.Nature communications · 2023Article
- Dynamic and transformable CuNature communications · 2023Article
- Structure sensitivity in gas sorption and conversion on metal-organic frameworks.Nature communications · 2023Article
- Electrochemical Sensor Based on Glassy-Carbon Electrode Modified with Dual-Ligand EC-MOFs Supported on rGO for BPA.Biosensors · 2022Article
- Realizing Broadband NIR Photodetection and Ultrahigh Responsivity with Ternary Blend Organic Photodetector.Nanomaterials (Basel, Switzerland) · 2022Article
- Crystalline hydrogen bonding of water molecules confined in a metal-organic framework.Communications chemistry · 2022Article
- MOFs in the time domain.Nature reviews. Chemistry · 2022Review
- Degradation Mechanism of Porous Metal-Organic Frameworks by In Situ Atomic Force Microscopy.Nanomaterials (Basel, Switzerland) · 2021Article
- High-performance polymer field-effect transistors: from the perspective of multi-level microstructures.Chemical science · 2020Review
- Unveiling the mechanism of lattice-mismatched crystal growth of a core-shell metal-organic framework.Chemical science · 2019Article
Corrections and comments
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Authors and funding
5 authors.
Funding
No grant is acknowledged in the PubMed record.
Abstract
The ability of porous coordination polymers to undergo reversible structural transformations in response to the presence of guest molecules has been intensively investigated for applications such as molecular separation, storage, sensing and signalling processes. Here we report on the direct observation of the highly guest-responsive nature of the surface of a single-crystalline porous coordination polymer, which consists of paddlewheel zinc clusters and two types of ligand, by in situ liquid-phase atomic force microscopy. Observations were carried out in solution at constant temperature (28 °C) by high-speed atomic force microscopy with lattice resolution. A sharp and reversible response to the presence or absence of biphenyl guest molecules was observed, under conditions that can scarcely induce the transformation of the bulk crystal. Additionally, by modulating the surface coordination equilibrium, layer-by-layer delamination events were captured in real time at every ~13 s per frame.
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Registered trials
Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.