ArticleNature communications2018
Design of an inherently-stable water oxidation catalyst.
Article in Nature communications, 2018. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 14 papers.
What it found
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The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.
The trial behind it
Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.
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Who cites it
14 citing papers in PubMed, 71 citations in OpenAlex.
- Occurrence, Stabilization, and Emerging Functions of the Early-Transition Metal Oxyanions Including Polyoxometalates in Various Complex Structures.Chemistry, an Asian journal · 2026Review
- Ion-Size Controlled Non-Classical Crystallization of Metal-Oxide Nanoparticles Covered with a Few Highly Charged Ligands.Journal of the American Chemical Society · 2026Article
- Ligand-Mediated Proton-Coupled Electron Injection into Reactive Cores of Soluble Macroanion-Like Complexes of Titanium Dioxide.Journal of the American Chemical Society · 2025Article
- Polyoxometalate Ligation of PbS Nanocrystals.Inorganic chemistry · 2025Article
- Myriophyllum Biochar-Supported Mn/Mg Nano-Composites as Efficient Periodate Activators to Enhance Triphenyl Phosphate Removal from Wastewater.Materials (Basel, Switzerland) · 2024Article
- Complexed Semiconductor Cores Activate Hexaniobate Ligands as Nucleophilic Sites for Solar-Light Reduction of COAngewandte Chemie (International ed. in English) · 2022Article
- Polyoxometalate-based nanocomposites for antitumor and antibacterial applications.Nanoscale advances · 2022Review
- Immobilization of a [CoACS materials Au · 2022Article
- BaActa crystallographica. Section E, Crystallographic communications · 2021Article
- Controlling the Size and Pattern Pitch of Ni(OH)Molecules (Basel, Switzerland) · 2020Article
- Crystalline Copper Selenide as a Reliable Non-Noble Electro(pre)catalyst for Overall Water Splitting.ChemSusChem · 2020Article
- Polyoxometalates on Functional Substrates: Concepts, Synergies, and Future Perspectives.Advanced science (Weinheim, Baden-Wurttemberg, Germany) · 2020Review
- A Low-Temperature Molecular Precursor Approach to Copper-Based Nano-Sized Digenite Mineral for Efficient Electrocatalytic Oxygen Evolution Reaction.Chemistry, an Asian journal · 2020Article
- The Reactivity and Stability of Polyoxometalate Water Oxidation Electrocatalysts.Molecules (Basel, Switzerland) · 2019Review
Corrections and comments
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Authors and funding
5 authors at 1 institution in 1 country.
Funding
No grant is acknowledged in the PubMed record.
Abstract
While molecular water-oxidation catalysts are remarkably rapid, oxidative and hydrolytic processes in water can convert their active transition metals to colloidal metal oxides or hydroxides that, while quite reactive, are insoluble or susceptible to precipitation. In response, we propose using oxidatively-inert ligands to harness the metal oxides themselves. This approach is demonstrated by covalently attaching entirely inorganic oxo-donor ligands (polyoxometalates) to 3-nm hematite cores, giving soluble anionic structures, highly resistant to aggregation, yet thermodynamically stable to oxidation and hydrolysis. Using orthoperiodate (at pH 8), and no added photosensitizers, the hematite-core complex catalyzes visible-light driven water oxidation for seven days (7600 turnovers) with no decrease in activity, far exceeding the documented lifetimes of molecular catalysts under turnover conditions in water. As such, a fundamental limitation of molecular complexes is entirely bypassed by using coordination chemistry to harness a transition-metal oxide as the reactive center of an inherently stable, homogeneous water-oxidation catalyst.
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Registered trials
Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.