ArticleChemical communications (Cambridge, England)2018
MIL-100Cr with open Cr sites for a record N
Article in Chemical communications (Cambridge, England), 2018. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 3 papers.
What it found
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The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.
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Who cites it
3 citing papers in PubMed.
- Ligand Geometry Regulated Architecture of Ultra-Microporous Flexible Guanidinium-Based Hydrogen-Bonded Organic Frameworks for Highly Selective Nitrous Oxide/Nitrogen Separation.Small (Weinheim an der Bergstrasse, Germany) · 2026Article
- MOFs with Open Metal(III) Sites for the Environmental Capture of Polar Volatile Organic Compounds.Angewandte Chemie (International ed. in English) · 2023Article
- Reversible ammonia uptake at room temperature in a robust and tunable metal-organic framework.RSC advances · 2022Article
Corrections and comments
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Authors and funding
9 authors.
Funding
Abstract
Nitrous oxide (N2O) is considered as the third most important greenhouse gas after carbon dioxide and methane and needs to be removed from air. Herein, we reported the metal-organic framework MIL-100Cr with open Cr sites for record N2O capture capacities of 5.78 mmol g-1 at 298 K and 8.25 mmol g-1 at 273 K, respectively. DFT calculations showed that the static binding energy of N2O on the open-Cr site is notably higher than that of N2, 72.5 kJ mol-1vs. 51.6 kJ mol-1, which enforces MIL-100Cr to exhibit extremely high N2O/N2 ideal adsorbed solution theory (IAST) gas separation selectivity up to 1000.
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Registered trials
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