ArticleOrganic & biomolecular chemistry2018
Iron(iii) chloride-catalyzed activation of glycosyl chlorides.
Article in Organic & biomolecular chemistry, 2018. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 13 papers.
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Who cites it
13 citing papers in PubMed.
- Article
- Progress on the synthesis and applications of the green non-ionic surfactant alkyl polyglycosides.RSC advances · 2025Review
- Cooperatively Catalyzed Activation of Thioglycosides with Iodine and Iron(III) Trifluoromethanesulfonate.Molecules (Basel, Switzerland) · 2025Article
- Ferric Chloride Promoted Glycosidation of Alkyl Thioglycosides.Molecules (Basel, Switzerland) · 2024Article
- SFox imidates as versatile glycosyl donors for chemical glycosylation.Organic & biomolecular chemistry · 2024Article
- Expanding the scope of stereoselective α-galactosylation using glycosyl chlorides.Bioorganic & medicinal chemistry · 2022Article
- Broadening the Scope of the Reverse Orthogonal Strategy for Oligosaccharide Synthesis.The Journal of organic chemistry · 2022Article
- Synthesis and Glycosidation of Anomeric Halides: Evolution from Early Studies to Modern Methods of the 21st Century.Chemical reviews · 2022Review
- Ferrocenium complex aidedRSC advances · 2021Article
- Bismuth(iii) triflate as a novel and efficient activator for glycosyl halides.Organic & biomolecular chemistry · 2021Article
- A Highly Efficient Glycosidation of Glycosyl Chlorides by Using Cooperative Silver(I) Oxide-Triflic Acid Catalysis.Chemistry (Weinheim an der Bergstrasse, Germany) · 2020Article
- Defining the Scope of the Acid-Catalyzed Glycosidation of Glycosyl Bromides.Chemistry (Weinheim an der Bergstrasse, Germany) · 2020Article
- Bromine-Promoted Glycosidation of Conformationally Superarmed Thioglycosides.Chemistry (Weinheim an der Bergstrasse, Germany) · 2019Article
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Authors and funding
2 authors.
Funding
Abstract
Glycosyl chlorides have historically been activated using harsh conditions and/or toxic stoichiometric promoters. More recently, the Ye and the Jacobsen groups showed that glycosyl chlorides can be activated under organocatalytic conditions. However, those reactions are slow, require specialized catalysts and high temperatures, but still provide only moderate yields. Presented herein is a simple method for the activation of glycosyl chlorides using abundant and inexpensive ferric chloride in catalytic amounts. Our preliminary results indicate that both benzylated and benzoylated glycosyl chlorides can be activated with 20 mol% of FeCl3.
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Registered trials
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