ArticleOrganic letters2018
Photocatalytic Oxyamination of Alkenes: Copper(II) Salts as Terminal Oxidants in Photoredox Catalysis.
Article in Organic letters, 2018. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 13 papers.
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Who cites it
13 citing papers in PubMed.
- Tuning light-driven oxidation of styrene inside water-soluble nanocages.Nature communications · 2024Article
- Cu(II) salts as terminal oxidants in visible-light photochemical oxidation reactions.Organic & biomolecular chemistry · 2023Review
- Light-induced homolysis of copper(ii)-complexes - a perspective for photocatalysis.Chemical science · 2023Review
- Radical Redox Annulations: A General Light-Driven Method for the Synthesis of Saturated Heterocycles.ACS catalysis · 2022Article
- Photons or Electrons? A Critical Comparison of Electrochemistry and Photoredox Catalysis for Organic Synthesis.Chemical reviews · 2022Review
- Decarboxylative cross-nucleophile coupling via ligand-to-metal charge transfer photoexcitation of Cu(II) carboxylates.Nature chemistry · 2022Article
- Copper-Mediated Radical-Polar Crossover Enables Photocatalytic Oxidative Functionalization of Sterically Bulky Alkenes.Journal of the American Chemical Society · 2021Article
- Continuous-Flow Synthesis of Pyrylium Tetrafluoroborates: Application to Synthesis of Katritzky Salts and Photoinduced Cationic RAFT Polymerization.Organic letters · 2021Article
- Oxidase reactions in photoredox catalysis.Chemical Society reviews · 2021Review
- AlkeneOrganic letters · 2020Article
- Site-Selective Alkoxylation of Benzylic C-H Bonds by Photoredox Catalysis.Angewandte Chemie (International ed. in English) · 2020Article
- Safe, sustainable and scalable.Nature chemistry · 2019Article
- Tandem copper and photoredox catalysis in photocatalytic alkene difunctionalization reactions.Beilstein journal of organic chemistry · 2019Article
Corrections and comments
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Authors and funding
4 authors.
Funding
Abstract
A photocatalytic method for the oxyamination of alkenes using simple nucleophilic nitrogen atom sources in place of prefunctionalized electrophilic nitrogen atom donors is reported. Copper(II) is an inexpensive, practical, and uniquely effective terminal oxidant for this process. In contrast to oxygen, peroxides, and similar oxidants commonly utilized in non-photochemical oxidative methods, the use of copper(II) as a terminal oxidant in photoredox reactions avoids the formation of reactive heteroatom-centered radical intermediates that can be incompatible with electron-rich functional groups. As a demonstration of the generality of this concept, it has been shown that diamination and deoxygenation reactions can also be accomplished using similar photooxidative conditions.
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Registered trials
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