ArticleChemistry (Weinheim an der Bergstrasse, Germany)2019
Koenigs-Knorr Glycosylation Reaction Catalyzed by Trimethylsilyl Trifluoromethanesulfonate.
Article in Chemistry (Weinheim an der Bergstrasse, Germany), 2019. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 15 papers.
What it found
Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.
The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.
The trial behind it
Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.
Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.
Who cites it
15 citing papers in PubMed.
- Progress on the synthesis and applications of the green non-ionic surfactant alkyl polyglycosides.RSC advances · 2025Review
- Cooperatively Catalyzed Activation of Thioglycosides with Iodine and Iron(III) Trifluoromethanesulfonate.Molecules (Basel, Switzerland) · 2025Article
- Silver Oxide Promoted Synthesis of AlphaThe Journal of organic chemistry · 2025Article
- Expedient Synthesis of Superarmed Glycosyl Donors via Oxidative Thioglycosidation of Glycals.Synthesis · 2024Article
- Overcoming Challenges in Chemical Glycosylation to Achieve Innovative Vaccine Adjuvants Possessing Enhanced TLR4 Activity.ACS omega · 2023Article
- Cooperatively Catalyzed Activation of Thioglycosides That Bypasses Intermediacy of Glycosyl Halides.Chemistry (Weinheim an der Bergstrasse, Germany) · 2023Article
- Expanding the scope of stereoselective α-galactosylation using glycosyl chlorides.Bioorganic & medicinal chemistry · 2022Article
- Synthesis and Glycosidation of Anomeric Halides: Evolution from Early Studies to Modern Methods of the 21st Century.Chemical reviews · 2022Review
- Bismuth(iii) triflate as a novel and efficient activator for glycosyl halides.Organic & biomolecular chemistry · 2021Article
- Stereocontrolled α-Galactosylation under Cooperative Catalysis.The Journal of organic chemistry · 2020Article
- Indolylthio Glycosides As Effective Building Blocks for Chemical Glycosylation.The Journal of organic chemistry · 2020Article
- A Highly Efficient Glycosidation of Glycosyl Chlorides by Using Cooperative Silver(I) Oxide-Triflic Acid Catalysis.Chemistry (Weinheim an der Bergstrasse, Germany) · 2020Article
- Diastereoselective spACS catalysis · 2020Article
- Defining the Scope of the Acid-Catalyzed Glycosidation of Glycosyl Bromides.Chemistry (Weinheim an der Bergstrasse, Germany) · 2020Article
- Bromine-Promoted Glycosidation of Conformationally Superarmed Thioglycosides.Chemistry (Weinheim an der Bergstrasse, Germany) · 2019Article
Corrections and comments
PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.
Authors and funding
2 authors.
Funding
Abstract
The discovery that traditional silver(I)-oxide-promoted glycosidations of glycosyl bromides (Koenigs-Knorr reaction) can be greatly accelerated in the presence of catalytic trimethylsilyl trifluoromethanesulfonate (TMSOTf) is reported. The reaction conditions are very mild that allowed for maintaining a practically neutral pH and, at the same time, providing high rates and excellent glycosylation yields. In addition, unusual reactivity trends among a series of differentially protected glycosyl bromides were documented. In particular, benzoylated α-bromides were much more reactive than their benzylated counterparts under these conditions.
Indexed as
Identifiers
What OpenQuestion holds
Registered trials
Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.