ArticleJournal of the American Chemical Society2018
Catalytic Regio- and Enantioselective Haloazidation of Allylic Alcohols.
Article in Journal of the American Chemical Society, 2018. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 11 papers.
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Who cites it
11 citing papers in PubMed, 57 citations in OpenAlex.
- Photocatalytic anti-Markovnikov hydro- and haloazidation of alkenes.Nature communications · 2025Article
- Controllable Multihalogenation of a Non-native Substrate by the SyrB2 Iron Halogenase.ACS catalysis · 2024Article
- Stereoinvertive Nucleophilic Substitution at Quaternary Carbon Stereocenters of Cyclopropyl Ketones and Ethers.Angewandte Chemie (International ed. in English) · 2022Article
- Kinetic resolution of cyclic benzylic azides enabled by site- and enantioselective C(spNature communications · 2022Article
- Oxyenamides as Versatile Building Blocks for a Highly Stereoselective One-Pot Synthesis of the 1,3-Diamino-2-ol-Scaffold Containing Three Continuous Stereocenters.Angewandte Chemie (International ed. in English) · 2021Article
- Catalytic enantioselective bromohydroxylation of cinnamyl alcohols.RSC advances · 2021Article
- Ritter-enabled catalytic asymmetric chloroamidation of olefins.Chemical science · 2020Article
- H-bond donor-directed switching of diastereoselectivity in the Michael addition of α-azido ketones to nitroolefins.Chemical science · 2020Article
- A Convenient C-H Functionalization Platform for Pyrroloiminoquinone Alkaloid Synthesis.Tetrahedron · 2019Article
- Allylic azides: synthesis, reactivity, and the Winstein rearrangement.Organic & biomolecular chemistry · 2019Review
- Dative Directing Group Effects in Ti-Catalyzed [2+2+1] Pyrrole Synthesis: Chemo- and Regioselective Alkyne Heterocoupling.ACS catalysis · 2019Article
Corrections and comments
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Authors and funding
4 authors at 1 institution in 1 country.
Funding
Abstract
Herein we report a highly regio- and stereoselective haloazidation of allylic alcohols. This enantioselective reaction uses readily available materials and can be performed on a variety of alkyl-substituted alkenes and can incorporate either bromine or chlorine as the electrophilic halogen component. Both halide and azido groups of the resulting products can be transformed into valuable building blocks with complete stereospecificity. The first example of an enantioselective 1,4-haloazidation of a conjugated diene is reported as well as its application to a concise synthesis of an aza-sugar.
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