ArticleChemical communications (Cambridge, England)2018
Isolation and characterization of a high-spin mixed-valent iron dinitrogen complex.
Article in Chemical communications (Cambridge, England), 2018. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 7 papers.
What it found
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The trial behind it
Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.
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Who cites it
7 citing papers in PubMed, 19 citations in OpenAlex.
- Redox State-Dependent Dinitrogen Binding by an Isocyanide Analogue of 15eAngewandte Chemie (International ed. in English) · 2026Article
- Formation of a diiron-(μ-ηActa crystallographica. Section C, Structural chemistry · 2024Article
- Mössbauer and Nuclear Resonance Vibrational Spectroscopy Studies of Iron Species Involved in N-N Bond Cleavage.Inorganic chemistry · 2023Article
- Lewis Structures and the Bonding Classification of End-on Bridging Dinitrogen Transition Metal Complexes.Journal of the American Chemical Society · 2023Review
- Dinitrogen Coordination to a High-Spin Diiron(I/II) Species.Angewandte Chemie (International ed. in English) · 2022Article
- The influences of carbon donor ligands on biomimetic multi-iron complexes for NChemical science · 2020Article
- Activation of Dinitrogen by Polynuclear Metal Complexes.Chemical reviews · 2020Review
Corrections and comments
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Authors and funding
7 authors at 3 institutions in 1 country.
Funding
Abstract
We report a rare example of a mixed-valence iron compound with an FeNNFe core, which gives insight into the structural, spectroscopic, and magnetic influences of single-electron reductions and oxidations. In the new compound, the odd electron is localized as judged from Mössbauer spectra at 80 K and infrared spectra at room temperature, and the backbonding into the N2 unit is intermediate between diiron(i) and diiron(0) congeners. Magnetic susceptibility and relaxation studies on the series of FeNNFe compounds show significant magnetic anisotropy, but through-barrier pathways enable fairly rapid magnetic relaxation.
Identifiers
What OpenQuestion holds
Registered trials
Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.