ArticleThe Journal of organic chemistry2018
Hyperconjugative Aromaticity and Antiaromaticity Control the Reactivities and π-Facial Stereoselectivities of 5-Substituted Cyclopentadiene Diels-Alder Cycloadditions.
Article in The Journal of organic chemistry, 2018. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 15 papers.
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Who cites it
15 citing papers in PubMed.
- Schleyer-type hyperconjugative aromaticity in CH isomers of diazoles revealed by DFT and NBO analysis.Scientific reports · 2026Article
- Impact of Transition-State Aromaticity on Selective Radical-Radical Coupling of Triarylimidazolyl Radicals.Journal of the American Chemical Society · 2025Article
- Computational Organic Chemistry: The Frontier for Understanding and Designing Bioorthogonal Cycloadditions.Topics in current chemistry (Cham) · 2024Review
- The application of aromaticity and antiaromaticity to reaction mechanisms.Fundamental research · 2023Review
- Computational study of an oxetane 4Tetrahedron letters · 2023Article
- Bioorthogonal 4Chemical communications (Cambridge, England) · 2023Article
- Spirocyclization enhances the Diels-Alder reactivities of geminally substituted cyclopentadienes and 4Journal of physical organic chemistry · 2023Article
- Three-Dimensional Fully π-Conjugated Macrocycles: When 3D-Aromatic and When 2D-Aromatic-in-3D?Journal of the American Chemical Society · 2022Article
- Geminal Repulsion Disrupts Diels-Alder Reactions of Geminally Substituted Cyclopentadienes and 4Tetrahedron · 2021Article
- Click Chemistry with Cyclopentadiene.Chemical reviews · 2021Review
- Antiaromaticity Gain Activates Tropone and Nonbenzenoid Aromatics as Normal-Electron-Demand Diels-Alder Dienes.Organic letters · 2020Article
- Differential Effects of Nitrogen Substitution in 5- and 6-Membered Aromatic Motifs.Chemistry (Weinheim an der Bergstrasse, Germany) · 2020Article
- Synthesis and Diels-Alder Reactivity of 4-Fluoro-4-Methyl-4International journal of molecular sciences · 2020Article
- Hyperconjugative aromaticity and protodeauration reactivity of polyaurated indoliums.Nature communications · 2019Article
- Hyperconjugative Antiaromaticity Activates 4Organic letters · 2019Article
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3 authors.
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Abstract
The reactivities and π-facial stereoselectivities of Diels-Alder reactions of 5-substituted cyclopentadienes were studied using density functional theory. Burnell and co-workers previously showed that the π-facial selectivities result from the energies required to distort the reactants into the transition state geometries. We have discovered the origins of these distortions. C
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