ArticleACS catalysis2018
Carvone-Derived P-Stereogenic Phosphines: Design, Synthesis, and Use in Allene-Imine [3 + 2] Annulation.
Article in ACS catalysis, 2018. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 18 papers.
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Who cites it
18 citing papers in PubMed.
- Synthesis through C(spAccounts of chemical research · 2025Article
- Hydrodealkenylative C(spJournal of the American Chemical Society · 2025Article
- Deacylative Homolysis of Ketone C(spJournal of the American Chemical Society · 2025Article
- Halodealkenylation: Ozonolysis and Catalytic FeOrganic letters · 2024Article
- Dealkenylative Functionalizations: Conversion of Alkene C(spSynthesis · 2024Article
- Hydrodealkenylative Cleavage of C(spOrganic syntheses; an annual publication of satisfactory methods for the preparation of organic chemicals · 2024Article
- Unveiling the Chemistry and Synthetic Potential of Catalytic Cycloaddition Reaction of Allenes: A Review.Molecules (Basel, Switzerland) · 2023Review
- Access to Enantiomerically Pure P-Stereogenic Primary Aminophosphine Sulfides under Reductive Conditions.Chemistry (Weinheim an der Bergstrasse, Germany) · 2022Article
- Dealkenylative Alkynylation Using Catalytic FeJournal of the American Chemical Society · 2022Article
- Phosphorus-Based Catalysis.ACS central science · 2021Review
- Dealkenylative Alkenylation: Formal σ-Bond Metathesis of Olefins.Angewandte Chemie (International ed. in English) · 2020Article
- Phosphine-Catalyzed (4+1) Annulation: Rearrangement of Allenylic Carbamates to 3-Pyrrolines through Phosphonium Diene Intermediates.ChemCatChem · 2020Article
- Catalytic Enantiodivergent Michael Addition by Subtle Adjustment of Achiral Amino Moiety of Dipeptide Phosphines.iScience · 2020Article
- Oxodealkenylative Cleavage of Alkene C(spAngewandte Chemie (International ed. in English) · 2020Article
- Chiral aminophosphines derived from hydroxyproline and their application in allene-imine [4 + 2] annulation.The Journal of antibiotics · 2019Article
- Hydrodealkenylative C(spScience (New York, N.Y.) · 2019Article
- Discussion Addendum for: Phosphine-Catalyzed [3 + 2] Annulation: Synthesis of Ethyl 5-(Organic syntheses; an annual publication of satisfactory methods for the preparation of organic chemicals · 2019Article
- Catalytic Enantioselective Synthesis of Guvacine Derivatives through [4 + 2] Annulations of Imines with α-Methylallenoates.Organic letters · 2018Article
Corrections and comments
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Authors and funding
3 authors.
Funding
Abstract
We have prepared a previously unreported family of P-stereogenic [2.2.1] bicyclic chiral phosphines through straightforward syntheses starting from the natural product carvone. This design rationale prompted the development of an unforeseen C-dealkenylation reaction. We have applied these organocatalysts in the asymmetric syntheses of a bevy of pyrrolines, obtained in high yields and enantioselectivities, including a biologically active small molecule, efsevin.
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Registered trials
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