ArticleRSC advances2018
Stoichiometric analysis of competing intermolecular hydrogen bonds using infrared spectroscopy.
Article in RSC advances, 2018. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 22 papers.
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The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.
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Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.
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Who cites it
22 citing papers in PubMed.
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- Aqueously Upcycled Lignin with Emergent Tribonegativity for Skin-Integrated Triboelectronics.Advanced materials (Deerfield Beach, Fla.) · 2026Article
- Improvement of dentin bonding via adhesive monomers with multiple hydrogen bonding moieties.Acta biomaterialia · 2025Article
- Hydrophobicity-Driven Enhancement of Hydrogen Bonding in Ionic Liquid Hybrid Solvents.The journal of physical chemistry. B · 2025Article
- Analysis of monomer ratios in a dimethacrylate mixture using positron annihilation spectroscopy.Scientific reports · 2025Article
- Preparation of Particle-Reinforced Resin Using Highly Functional ZnO Particle Filler Driven by Supramolecular Interactions.Materials (Basel, Switzerland) · 2025Article
- Manifestation of Donor-Acceptor Properties of N-Doped Polymer Carbon Dots During Hydrogen Bonds Formation in Different Solvents.Polymers · 2024Article
- Valorizing Biopolyester Suberin: Modification of Cellulose Nanocrystals and Performance Assessment in 3D-Printed Biobased Acrylates.ACS omega · 2024Article
- Intrinsically stretchable organic photovoltaics by redistributing strain to PEDOT:PSS with enhanced stretchability and interfacial adhesion.Nature communications · 2024Article
- Systematic Study of Different Types of Interactions in α-, β- and γ-Cyclodextrin: Quantum Chemical Investigation.Molecules (Basel, Switzerland) · 2024Article
- Lignin-derivable, thermoplastic, non-isocyanate polyurethanes with increased hydrogen-bonding content and toughnessMaterials advances · 2024Article
- Fragment-based drug nanoaggregation reveals drivers of self-assembly.Nature communications · 2023Article
- Novel antibacterial low-shrinkage-stress resin-based cement.Dental materials : official publication of the Academy of Dental Materials · 2022Article
- Thermosensitive Bioadhesive Hydrogels Based on Poly(Pharmaceutics · 2021Article
- Salt Cocrystal of Diclofenac Sodium-L-Proline: Structural, Pseudopolymorphism, and Pharmaceutics Performance Study.Pharmaceutics · 2020Article
- Development of Novel Silica-based Formulation of α-Lipoic Acid: Evaluation of Photo and Thermal Stability of the Encapsulated Drug.Pharmaceutics · 2020Article
- Intracellular Delivery of Anti-SMC2 Antibodies against Cancer Stem Cells.Pharmaceutics · 2020Article
- High-Performance Dental Adhesives Containing an Ether-Based Monomer.Journal of dental research · 2020Article
Corrections and comments
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Authors and funding
5 authors.
Funding
Abstract
We quantitatively analyze multiple hydrogen bonds in mixtures of two monomers: urethane dimethacrylate (UDMA) and triethylene glycol-divinylbenzyl ether (TEG-DVBE). The carbonyl stretching band in infrared (IR) absorption spectra is deconvoluted into free and hydrogen-bonded carbonyl groups. The amounts of the sub-components are determined for 21 mixture compositions and initially analyzed using a simple stoichiometric model (based on one dominant hydrogen acceptor group per monomer species) for the equilibrium state of hydrogen bond formation. However, our in-depth stoichiometric analysis suggests that at least two UDMA acceptor groups (carbonyl and alkoxy oxygens) and one TEG-DVBE acceptor group (ether oxygen) contribute to intermolecular hydrogen bonding interactions. This finding is further supported by a quantitative analysis of the hydrogen bonding effect on the N-H stretching band. Moreover, the equilibrium constants of these hydrogen bond formations confirm that the interassociation between UDMA and TEG-DVBE is non-negligible in comparison to the UDMA selfassociations. Such quantitative information on intermolecular interactions provides insight into the effect of hydrogen bonding on the copolymerization kinetics of these monomer mixtures.
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Registered trials
Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.