ArticleAngewandte Chemie (International ed. in English)2018
Switch Catalysis To Deliver Multi-Block Polyesters from Mixtures of Propene Oxide, Lactide, and Phthalic Anhydride.
Article in Angewandte Chemie (International ed. in English), 2018. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 23 papers.
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Who cites it
23 citing papers in PubMed.
- Access to Microstructurally Complex Block Copolymers via Switchable Ring-Opening Polymerization of Cyclic Ester Mixtures.Macromolecules · 2025Article
- Depolymerization within a Circular Plastics System.Chemical reviews · 2024Review
- A recyclable polyester library from reversible alternating copolymerization of aldehyde and cyclic anhydride.Nature communications · 2023Article
- Salen-like Chromium and Aluminum Complexes as Catalysts in the Copolymerization of Epoxides with Cyclic Anhydrides for the Synthesis of Polyesters.International journal of molecular sciences · 2023Article
- Chromium Complexes Supported by Salen-Type Ligands for the Synthesis of Polyesters, Polycarbonates, and Their Copolymers through Chemoselective Catalysis.International journal of molecular sciences · 2023Article
- One-pot synthesis of hyperbranched polymers via visible light regulated switchable catalysis.Nature communications · 2023Article
- Catalysts as Key Enablers for the Synthesis of Bioplastics with Sophisticated Architectures.Chemistry (Weinheim an der Bergstrasse, Germany) · 2023Review
- Chain end-group selectivity using an organometallic Al(iii)/K(i) ring-opening copolymerization catalyst delivers high molar mass, monodisperse polyesters.Chemical science · 2022Article
- Lithium achieves sequence selective ring-opening terpolymerisation (ROTERP) of ternary monomer mixtures.Chemical science · 2022Article
- Zr(IV) Catalyst for the Ring-Opening Copolymerization of Anhydrides (A) with Epoxides (B), Oxetane (B), and Tetrahydrofurans (C) to Make ABB- and/or ABC-Poly(ester-Journal of the American Chemical Society · 2022Article
- One-step synthesis of sequence-controlled multiblock polymers with up to 11 segments from monomer mixture.Nature communications · 2022Article
- Mg(ii) heterodinuclear catalysts delivering carbon dioxide derived multi-block polymers.Chemical science · 2021Article
- Heterodinuclear Zn(II), Mg(II) or Co(III) with Na(I) Catalysts for Carbon Dioxide and Cyclohexene Oxide Ring Opening Copolymerizations.Chemistry (Weinheim an der Bergstrasse, Germany) · 2021Article
- Switchable Polymerization Catalysis Using a Tin(II) Catalyst and Commercial Monomers to Toughen Poly(l-lactide).ACS macro letters · 2021Article
- Sequence Control from Mixtures: Switchable Polymerization Catalysis and Future Materials Applications.Journal of the American Chemical Society · 2021Article
- Heterotrimetallic Carbon Dioxide Copolymerization and Switchable Catalysts: Sodium is the Key to High Activity and Unusual Selectivity.Angewandte Chemie (International ed. in English) · 2021Article
- Bio-based and Degradable Block Polyester Pressure-Sensitive Adhesives.Angewandte Chemie (International ed. in English) · 2020Article
- Triblock polyester thermoplastic elastomers with semi-aromatic polymer end blocks by ring-opening copolymerization.Chemical science · 2020Article
- Understanding metal synergy in heterodinuclear catalysts for the copolymerization of CONature chemistry · 2020Article
- Switchable Catalysis Improves the Properties of COJournal of the American Chemical Society · 2020Article
Corrections and comments
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Authors and funding
3 authors.
Funding
Abstract
Switchable polymerisation catalysis enables block polymer sequence selectivity from monomer mixtures, resulting in the formation of multiblock polyesters. The aluminium salphen catalyst switches between two different polymerisation mechanisms and selectively enchains mixtures of commercially available monomers: lactide, phthalic anhydride, and propene oxide. Sequential monomer mixture additions yield multi-block polyesters featuring 3, 7, 11, 15, 19, 23, and 27 blocks. The unparalleled catalytic selectivity can be used to access completely new multi-block polyesters relevant for future applications.
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Registered trials
Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.