Evidence map›Paper›PMID 30361549›Full record

ArticleNature communications2018

Enabling nanoscale flexoelectricity at extreme temperature by tuning cation diffusion.

Leopoldo Molina-Luna, Shuai Wang, Yevheniy Pivak, Alexander Zintler, Héctor H Pérez-Garza, Ronald G Spruit, Qiang Xu, Min Yi, Bai-Xiang Xu, Matias Acosta

Abstract read
In one paragraph

Article in Nature communications, 2018. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 3 papers.

0numbers the graph read from it
0cells of the map it votes in
3citing papers in PubMed
–field-weighted citation impact
1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

The trial behind it

Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.

Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.

3 · Its place in the literature

Who cites it

3 citing papers in PubMed.

  1. Article
  2. Article
  3. Article
4 · The record

Corrections and comments

PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.

5 · Who and what money

Authors and funding

10 authors.

Leopoldo Molina-LunaDepartment of Materials and Earth Sciences, Advanced Electron Microscopy (AEM) Group, Technische Universität Darmstadt, Alarich-Weiss-Strasse 2, 64287, Darmstadt, Germany. molina@aem.tu-darmstadt.de.ORCID http://orcid.org/0000-0002-9412-8093
Shuai WangDepartment of Materials and Earth Sciences, Mechanics of Functional Materials Division, Technische Universität Darmstadt, Otto-Berndt-Strasse 3, 64287, Darmstadt, Germany.ORCID http://orcid.org/0000-0002-3743-350X
Yevheniy PivakDENSsolutions, Informaticalaan 12, 2628ZD, Delft, Netherlands.
Alexander ZintlerDepartment of Materials and Earth Sciences, Advanced Electron Microscopy (AEM) Group, Technische Universität Darmstadt, Alarich-Weiss-Strasse 2, 64287, Darmstadt, Germany.
Héctor H Pérez-GarzaDENSsolutions, Informaticalaan 12, 2628ZD, Delft, Netherlands.
Ronald G SpruitDENSsolutions, Informaticalaan 12, 2628ZD, Delft, Netherlands.ORCID http://orcid.org/0000-0003-2826-2670
Qiang XuDENSsolutions, Informaticalaan 12, 2628ZD, Delft, Netherlands.
Min YiDepartment of Materials and Earth Sciences, Mechanics of Functional Materials Division, Technische Universität Darmstadt, Otto-Berndt-Strasse 3, 64287, Darmstadt, Germany.ORCID http://orcid.org/0000-0001-7672-3107
Bai-Xiang XuDepartment of Materials and Earth Sciences, Mechanics of Functional Materials Division, Technische Universität Darmstadt, Otto-Berndt-Strasse 3, 64287, Darmstadt, Germany.ORCID http://orcid.org/0000-0001-5906-5341
Matias AcostaDepartment of Materials and Earth Sciences, FG Nichtmetallische-Anorganische Werkstoffe, Technische Universität Darmstadt, Alarich-Weiss-Strasse 2, 64287, Darmstadt, Germany. ma771@cam.ac.uk.ORCID http://orcid.org/0000-0001-9504-883X

Funding

Deutsche Forschungsgemeinschaft (German Research Foundation) INST163/2951Deutsche Forschungsgemeinschaft (German Research Foundation) MO 3010/3-1Deutsche Forschungsgemeinschaft (German Research Foundation) RO954/22-1EC | Seventh Framework Programme (European Union Seventh Framework Programme) 312483/ESTEEM2Hessisches Ministerium für Wissenschaft und Kunst (Hessen State Ministry of Higher Education, Research and the Arts) LOEWE RESPONSE
6 · The paper itself

Abstract

Any dielectric material under a strain gradient presents flexoelectricity. Here, we synthesized 0.75 sodium bismuth titanate -0.25 strontium titanate (NBT-25ST) core-shell nanoparticles via a solid-state chemical reaction directly inside a transmission electron microscope (TEM) and observed domain-like nanoregions (DLNRs) up to an extreme temperature of 800 °C. We attribute this abnormal phenomenon to a chemically induced lattice strain gradient present in the core-shell nanoparticle. The strain gradient was generated by controlling the diffusion of strontium cations. By combining electrical biasing and temperature-dependent in situ TEM with phase field simulations, we analyzed the resulting strain gradient and local polarization distribution within a single nanoparticle. The analysis confirms that a local symmetry breaking, occurring due to a strain gradient (i.e. flexoelectricity), accounts for switchable polarization beyond the conventional temperature range of existing polar materials. We demonstrate that polar nanomaterials can be obtained through flexoelectricity at extreme temperature by tuning the cation diffusion.

Identifiers

PMID30361549
PMCPMC6202390

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Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.