ArticleJournal of the American Chemical Society2018
Mechanism and Origins of Chemo- and Stereoselectivities of Aryl Iodide-Catalyzed Asymmetric Difluorinations of β-Substituted Styrenes.
Article in Journal of the American Chemical Society, 2018. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 26 papers.
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Who cites it
26 citing papers in PubMed.
- Dyotropic Rearrangement of Hypervalent Iodine Species: Migrative Heterofunctionalization of Quaternary Carbons.Angewandte Chemie (International ed. in English) · 2026Article
- Chiral hypervalent iodine catalyzed stereoselective skeletal editing of pyrimidine fused heterocycles.Nature communications · 2025Article
- Harnessing Phenonium Ions in Synthesis.Angewandte Chemie (International ed. in English) · 2025Review
- Mechanistic insights into hydroxy(tosyloxy)iodobenzene-mediated ditosyloxylation of chalcones: a DFT study.Beilstein journal of organic chemistry · 2025Article
- Diastereodivergent nucleophile-nucleophile alkene chlorofluorination.Nature chemistry · 2024Article
- Hypervalent Iodine-Catalyzed Fluorination of Diene-Containing Compounds: A Computational Study.Molecules (Basel, Switzerland) · 2024Article
- Predicting bond dissociation energies of cyclic hypervalent halogen reagents using DFT calculations and graph attention network model.Beilstein journal of organic chemistry · 2024Article
- Regioselective, catalytic 1,1-difluorination of enynes.Nature chemistry · 2023Article
- Integrating I(I)/I(III) catalysis in reaction cascade design enables the synthesis of gem-difluorinated tetralins from cyclobutanols.Nature communications · 2023Article
- Theoretical Study on the Origin of Abnormal Regioselectivity in Ring-Opening Reaction of Hexafluoropropylene Oxide.Molecules (Basel, Switzerland) · 2023Article
- Catalytic, Regioselective 1,4-Fluorodifunctionalization of Dienes.Angewandte Chemie (International ed. in English) · 2023Article
- Stereocontrolled Synthesis of Fluorinated Isochromans via Iodine(I)/Iodine(III) Catalysis.Angewandte Chemie (International ed. in English) · 2022Article
- Hypervalent iodine-mediated β-difluoroalkylboron synthesisChemical science · 2022Article
- Mechanism-Dependent Selectivity: Fluorocyclization of Unsaturated Carboxylic Acids or Alcohols by Hypervalent Iodine.Frontiers in chemistry · 2022Article
- Electrophilic Fluorination of Alkenes via Bora-Wagner-Meerwein Rearrangement. Access to β-Difluoroalkyl Boronates.Angewandte Chemie (International ed. in English) · 2021Article
- Stereoselective Installation of Five Contiguous Stereogenic Centers in a Double Aldol-Tishchenko Cascade and Evaluation of the Key Transition State through DFT Calculation.Organic letters · 2021Article
- Organocatalytic enantioselective dearomatization of thiophenes by 1,10-conjugate addition of indole imine methides.Nature communications · 2021Article
- Data Science Meets Physical Organic Chemistry.Accounts of chemical research · 2021Article
- Formation of synthetically relevant CFRSC advances · 2021Article
- A Chiral Pentafluorinated Isopropyl Group via Iodine(I)/(III) Catalysis.Angewandte Chemie (International ed. in English) · 2021Article
Corrections and comments
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Authors and funding
5 authors.
Funding
Abstract
The mechanism of the aryl iodide-catalyzed asymmetric migratory geminal difluorination of β-substituted styrenes ( Banik et al. Science 2016, 353, 51 ) has been explored with density functional theory computations. The computed mechanism consists of (a) activation of iodoarene difluoride (ArIF
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Registered trials
Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.