ArticleOrganic letters2018
Synthesis of Trisubstituted Alkenyl Boronic Esters from Alkenes Using the Boryl-Heck Reaction.
Article in Organic letters, 2018. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 8 papers.
What it found
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Who cites it
8 citing papers in PubMed, 43 citations in OpenAlex.
- Pd-Catalyzed C(spThe Journal of organic chemistry · 2024Article
- Iterative Dual-Metal and Energy Transfer Catalysis Enables Stereodivergence in Alkyne Difunctionalization: Carboboration as Case Study.ACS catalysis · 2023Article
- Pd-Catalyzed Cross-Couplings: On the Importance of the Catalyst Quantity Descriptors, mol % and ppm.Organic process research & development · 2022Review
- Olefin Functionalization/Isomerization Enables Stereoselective Alkene Synthesis.Nature catalysis · 2021Article
- Synthesis of 1,1-Diboryl Alkenes Using the Boryl-Heck Reaction.Organic letters · 2021Article
- Visible Light-Induced Pd-Catalyzed Alkyl-Heck Reaction of Oximes.ACS catalysis · 2021Article
- Regio- and Stereoselective Thianthrenation of Olefins To Access Versatile Alkenyl Electrophiles.Angewandte Chemie (International ed. in English) · 2020Article
- Cross-Coupling of Heteroatomic Electrophiles.Chemical reviews · 2019Review
Corrections and comments
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Authors and funding
2 authors at 1 institution in 1 country.
Funding
Abstract
The direct borylation of disubstituted alkenes is reported. These conditions allow for the conversion of a variety 1,1- and 1,2-disubstituted alkenes to trisubstituted alkenyl boronic esters with outstanding yields and excellent E/ Z selectivities. The utility of this reaction has been demonstrated with several downstream functionalization reactions, which allow access to diverse, stereodefined, functionalized olefins. Mechanistic studies are consistent with a boryl-Heck pathway.
Identifiers
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Registered trials
Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.