ArticleNature communications2018
Anisotropic energy transfer in crystalline chromophore assemblies.
Article in Nature communications, 2018. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 14 papers.
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Who cites it
14 citing papers in PubMed.
- Long-Range Exciton Transport in Anthracene-Based Supramolecular Mesostructures and Its Control by Surface Plasmons.Nano letters · 2026Article
- A Dual-Role Amphiphilic Photosensitizer: Enhancing Structural Uniformity and Optical Properties of Langmuir Monolayers.Langmuir : the ACS journal of surfaces and colloids · 2026Article
- Dual-functional silver nanoparticle-enhanced ZnO nanorods for improved reactive oxygen species generation and cancer treatment.iScience · 2025Article
- Development of artificial photosystems based on designed proteins for mechanistic insights into photosynthesis.Protein science : a publication of the Protein Society · 2024Review
- Designing Single-Atom Active Sites on spAdvanced science (Weinheim, Baden-Wurttemberg, Germany) · 2023Article
- Connecting the dots for fundamental understanding of structure-photophysics-property relationships of COFs, MOFs, and perovskites using a Multiparticle Holstein Formalism.Chemical science · 2023Review
- Enhancing Dynamic Spectral Diffusion in Metal-Organic Frameworks through Defect Engineering.Journal of the American Chemical Society · 2023Article
- α-FeJournal of nanobiotechnology · 2021Article
- 2D Porphyrinic Metal-Organic Frameworks Featuring Rod-Shaped Secondary Building Units.Molecules (Basel, Switzerland) · 2021Article
- Interplay of structural dynamics and electronic effects in an engineered assembly of pentacene in a metal-organic framework.Chemical science · 2021Article
- Modular Synthesis of trans-AChemistry (Weinheim an der Bergstrasse, Germany) · 2021Article
- Tuning Optical Properties by Controlled Aggregation: Electroluminescence Assisted by Thermally-Activated Delayed Fluorescence from Thin Films of Crystalline Chromophores.Chemistry (Weinheim an der Bergstrasse, Germany) · 2020Article
- Exciton Coupling and Conformational Changes Impacting the Excited State Properties of Metal Organic Frameworks.Molecules (Basel, Switzerland) · 2020Article
- A de novo strategy for predictive crystal engineering to tune excitonic coupling.Nature communications · 2019Article
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Authors and funding
13 authors.
Funding
No grant is acknowledged in the PubMed record.
Abstract
An ideal material for photon harvesting must allow control of the exciton diffusion length and directionality. This is necessary in order to guide excitons to a reaction center, where their energy can drive a desired process. To reach this goal both of the following are required; short- and long-range structural order in the material and a detailed understanding of the excitonic transport. Here we present a strategy to realize crystalline chromophore assemblies with bespoke architecture. We demonstrate this approach by assembling anthracene dibenzoic acid chromophore into a highly anisotropic, crystalline structure using a layer-by-layer process. We observe two different types of photoexcited states; one monomer-related, the other excimer-related. By incorporating energy-accepting chromophores in this crystalline assembly at different positions, we demonstrate the highly anisotropic motion of the excimer-related state along the [010] direction of the chromophore assembly. In contrast, this anisotropic effect is inefficient for the monomer-related excited state.
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