ArticleChemical Society reviews2018
Beyond olefins: new metathesis directions for synthesis.
Article in Chemical Society reviews, 2018. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 22 papers.
What it found
Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.
The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.
The trial behind it
Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.
Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.
Who cites it
22 citing papers in PubMed, 113 citations in OpenAlex.
- Transition Metal-Free Borata-Alkene/Alkyne Metathesis Enables Access to Cyclopentenes.Angewandte Chemie (International ed. in English) · 2026Article
- Hydrazine-mediated carbonyl-alkyne/allene reductive olefination.Nature communications · 2026Article
- Theoretical Investigations of Substrate Behavior in FeClACS omega · 2025Article
- Full on-device manipulation of olefin metathesis for precise manufacturing.Nature nanotechnology · 2025Article
- Alkene Diversification through a Molecular Recasting Strategy Enabled byResearch (Washington, D.C.) · 2025Article
- Cyclization Strategies in Carbonyl-Olefin Metathesis: An Up-to-Date Review.Molecules (Basel, Switzerland) · 2024Review
- A metal-catalysed functional group metathesis approach to the carbon isotope labelling of carboxylic acids.Nature chemistry · 2024Article
- Enantioselective synthesis of α,α-diarylketones by sequential visible light photoactivation and phosphoric acid catalysis.Science advances · 2023Article
- Iron-Catalyzed Olefin Metathesis: Recent Theoretical and Experimental Advances.Chemistry (Weinheim an der Bergstrasse, Germany) · 2022Review
- Explaining Regiodivergent Vinylations with Vinylbenziodoxolones.Angewandte Chemie (International ed. in English) · 2022Article
- Hydrogen Bonding Networks Enable Brønsted Acid-Catalyzed Carbonyl-Olefin Metathesis.Angewandte Chemie (International ed. in English) · 2022Article
- Rhodium-catalyzed intramolecular reductive aldol-type cyclization: Application for the synthesis of a chiral necic acid lactone.Beilstein journal of organic chemistry · 2022Article
- Thiophosphonium-Alkyne Cycloaddition Reactions: A Heavy Congener of the Carbonyl-Alkyne Metathesis.Inorganic chemistry · 2021Article
- Ni-catalyzed regio- and stereo-defined intermolecular cross-electrophile dialkylation of alkynes without directing group.Nature communications · 2021Article
- Brønsted-Acid-Catalyzed Intramolecular Carbonyl-Olefin Reactions: Interrupted Metathesis vs Carbonyl-Ene Reaction.The Journal of organic chemistry · 2021Article
- Iron in a Cage: Fixation of a Fe(II)tpyAngewandte Chemie (International ed. in English) · 2020Article
- Ring-opening carbonyl-olefin metathesis of norbornenes.Chemical science · 2020Article
- Characterizing Lewis Pairs Using Titration Coupled with In Situ Infrared Spectroscopy.Journal of visualized experiments : JoVE · 2020Article
- Investigation of Lewis Acid-Carbonyl Solution Interactions via Infrared-Monitored Titration.The Journal of organic chemistry · 2020Article
- Synthesis of 2ACS catalysis · 2019Article
Corrections and comments
PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.
Authors and funding
3 authors at 1 institution in 1 country.
Funding
Abstract
The olefin-olefin metathesis reaction has emerged as one of the most important carbon-carbon bond-forming reactions, as illustrated by its wide use in the synthesis of complex molecules, natural products and pharmaceuticals. The corresponding metathesis reaction between carbonyls and olefins or alkynes similarly allows for the formation of carbon-carbon bonds. Although these variants are far less developed and utilized in organic synthesis, they possess attractive qualities that have prompted chemists to incorporate and explore these modes of reactivity in complex molecule synthesis. This review highlights selected examples of carbonyl-olefin and carbonyl-alkyne metathesis reactions in organic synthesis, in particular in the total synthesis of natural products and complex molecules, and provides an overview of current advantages and limitations.
Identifiers
What OpenQuestion holds
Registered trials
Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.