ArticleChemical science2018
Catalyst-dependent selectivity in sulfonium ylide cycloisomerization reactions.
Article in Chemical science, 2018. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 7 papers.
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Who cites it
7 citing papers in PubMed.
- Gold(I)-Catalyzed Tandem 1,2-Indole Migration-Cyclopropanation Reactions of 3-Propargylindoles with Olefins.Organic letters · 2025Article
- Intramolecular Oxyalkylation of Unactivated Alkenes.Tetrahedron · 2024Article
- Empowering boronic acids as hydroxyl synthons for aryne induced three-component coupling reactions.Chemical science · 2023Article
- Gold-Catalyzed Cycloisomerization of Sulfur Ylides to Dihydrobenzothiepines.Chemistry (Weinheim an der Bergstrasse, Germany) · 2020Article
- Bond-Forming and -Breaking Reactions at Sulfur(IV): Sulfoxides, Sulfonium Salts, Sulfur Ylides, and Sulfinate Salts.Chemical reviews · 2019Article
- Article
- A Catalytic Cross-Olefination of Diazo Compounds with Sulfoxonium Ylides.Angewandte Chemie (International ed. in English) · 2018Article
Corrections and comments
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Authors and funding
6 authors.
Funding
No grant is acknowledged in the PubMed record.
Abstract
Divergent catalysis is an emerging field whereby access to structurally diverse compounds from a common precursor is achieved through controlled reaction pathways. Herein we present an unusual example of π-acid catalyst dependent selectivity in the cycloisomerization of alkene-tethered sulfonium ylides. Computational mechanistic studies revealed how the ability of palladium to cycle through oxidation states largely controls the selectivity.
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Registered trials
Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.