Evidence map›Paper›PMID 30310585›Full record

ArticleChemical science2018

Mononuclear complexes of a tridentate redox-active ligand with sulfonamido groups: structure, properties, and reactivity.

Sarah A Cook, Justin A Bogart, Noam Levi, Andrew C Weitz, Curtis Moore, Arnold L Rheingold, Joseph W Ziller, Michael P Hendrich, A S Borovik

Abstract read
In one paragraph

Article in Chemical science, 2018. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 6 papers.

0numbers the graph read from it
0cells of the map it votes in
6citing papers in PubMed
–field-weighted citation impact
1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

The trial behind it

Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.

Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.

3 · Its place in the literature

Who cites it

6 citing papers in PubMed.

  1. Article
  2. Article
  3. Article
  4. Review
  5. Stabilizing a NiInorganica chimica acta · 2019
    Article
  6. Catalytic β C-H aminationChemical science · 2019
    Article
4 · The record

Corrections and comments

PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.

5 · Who and what money

Authors and funding

9 authors.

Sarah A CookDepartment of Chemistry , University of California-Irvine , 1102 Natural Sciences II , Irvine , California 92697 , USA . Email: aborovik@uci.edu.
Justin A BogartDepartment of Chemistry , University of California-Irvine , 1102 Natural Sciences II , Irvine , California 92697 , USA . Email: aborovik@uci.edu.
Noam LeviDepartment of Chemistry , University of California-Irvine , 1102 Natural Sciences II , Irvine , California 92697 , USA . Email: aborovik@uci.edu.
Andrew C WeitzDepartment of Chemistry , Carnegie Melon University , Pittsburgh , Pennsylvania 15213 , USA.
Curtis MooreDepartment of Chemistry and Biochemistry , University of California-San Diego , San Diego , California 92093 , USA.
Arnold L RheingoldDepartment of Chemistry and Biochemistry , University of California-San Diego , San Diego , California 92093 , USA.
Joseph W ZillerDepartment of Chemistry , University of California-Irvine , 1102 Natural Sciences II , Irvine , California 92697 , USA . Email: aborovik@uci.edu.
Michael P HendrichDepartment of Chemistry , Carnegie Melon University , Pittsburgh , Pennsylvania 15213 , USA.ORCID 0000-0003-4775-0389
A S BorovikDepartment of Chemistry , University of California-Irvine , 1102 Natural Sciences II , Irvine , California 92697 , USA . Email: aborovik@uci.edu.ORCID 0000-0001-5049-9952

Funding

Upgrade for an Electron Paramagnetic Resonance SpectrometerR37GM050781 · NIGMS · UNIVERSITY OF CALIFORNIA-IRVINE · PI BOROVIK, ANDREW S. · 2016 to 2025
$4.1M
HYDROGEN BONDING CAVITY MOTIFS ABOUT METAL IONSR01GM050781 · NIGMS · UNIVERSITY OF KANSAS LAWRENCE · PI BOROVIK, ANDREW S. · 1999 to 2015
$3.9M
EPR and Mossbauer Characterization of Mn and Fe Proteins, Models, IntermediatesR01GM077387 · NIGMS · CARNEGIE-MELLON UNIVERSITY · PI HENDRICH, MICHAEL P · 2006 to 2019
$2.9M
Integrated Control of the Primary and Secondary Coordination Spheres in Synthetic Monooxygenase Mimics: Probing Dioxygen Activation at a Single Metal Site.F32GM120837 · NIGMS · UNIVERSITY OF CALIFORNIA-IRVINE · PI BOGART, JUSTIN · 2017 to 2018
$78k
NIGMS NIH HHS F32 GM120837NIGMS NIH HHS R01 GM050781NIGMS NIH HHS R01 GM077387NIGMS NIH HHS R37 GM050781
6 · The paper itself

Abstract

The design of molecular complexes of earth-abundant first-row transition metals that can catalyze multi-electron C-H bond activation processes is of interest for achieving efficient, low-cost syntheses of target molecules. To overcome the propensity of these metals to perform single-electron processes, redox-active ligands have been utilized to provide additional electron equivalents. Herein, we report the synthesis of a novel redox active ligand, [ibaps]

Identifiers

PMID30310585
PMCPMC6115676

What OpenQuestion holds

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Registered trials

None linked

Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.