Evidence map›Paper›PMID 30310569›Full record

ArticleChemical science2018

Silylated cyclopentadienes as competent silicon Lewis acid catalysts.

M Alex Radtke, Tristan H Lambert

Abstract read
In one paragraph

Article in Chemical science, 2018. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 5 papers.

0numbers the graph read from it
0cells of the map it votes in
5citing papers in PubMed
–field-weighted citation impact
1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

The trial behind it

Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.

Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.

3 · Its place in the literature

Who cites it

5 citing papers in PubMed.

  1. Article
  2. Article
  3. Hydrogen Bond Donor Catalyzed Cationic Polymerization of Vinyl Ethers.Angewandte Chemie (International ed. in English) · 2021
    Article
  4. An Experimental Acidity Scale for Intramolecularly Stabilized Silyl Lewis Acids.Chemistry (Weinheim an der Bergstrasse, Germany) · 2019
    Article
  5. Article
4 · The record

Corrections and comments

PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.

5 · Who and what money

Authors and funding

2 authors.

M Alex RadtkeDepartment of Chemistry , Columbia University , New York , NY 10027 , USA.
Tristan H LambertDepartment of Chemistry , Columbia University , New York , NY 10027 , USA.ORCID 0000-0002-7720-3290

Funding

Enantioselective Bronsted Acid Catalysis with Chiral CyclopentadienesR01GM120205 · NIGMS · CORNELL UNIVERSITY · PI LAMBERT, TRISTAN H · 2016 to 2017
$601k
NIGMS NIH HHS R01 GM120205
6 · The paper itself

Abstract

The synthesis and characterization of silicon Lewis acid complexes that incorporate highly electron-deficient cyclopentadienes is reported. Several pentacarboxycyclopentadienyl and monocarboxytetracyanocyclopentadienyl complexes were prepared. A comparison of their reactivities for catalysis of the allylation of an electron-deficient benzaldehyde was established. The use of a monocarboxytetracyano silylium donor was shown to be effective for the allylation or arylation of a variety of electrophiles

Identifiers

PMID30310569
PMCPMC6115689

What OpenQuestion holds

Textmetadata
LicenceCC BY
Read underepoch 390

Registered trials

None linked

Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.