Evidence map›Paper›PMID 30310566›Full record

ArticleChemical science2018

Nitric oxide activation facilitated by cooperative multimetallic electron transfer within an iron-functionalized polyoxovanadate-alkoxide cluster.

F Li, R L Meyer, S H Carpenter, L E VanGelder, A W Nichols, C W Machan, M L Neidig, E M Matson

Abstract read
PubMed Full text at PMC Publisher
In one paragraph

Article in Chemical science, 2018. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 5 papers.

0numbers the graph read from it
0cells of the map it votes in
5citing papers in PubMed
–field-weighted citation impact
1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

The trial behind it

Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.

Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.

3 · Its place in the literature

Who cites it

5 citing papers in PubMed.

  1. The Elusive Mononitrosylated [FeAngewandte Chemie (International ed. in English) · 2022
    Article
  2. Article
  3. Review
  4. Mononuclear, Nonheme, High-Spin {FeNO}Inorganic chemistry · 2019
    Article
  5. A Mononuclear, Nonheme FeJournal of the American Chemical Society · 2019
    Article
4 · The record

Corrections and comments

PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.

5 · Who and what money

Authors and funding

8 authors.

F LiDepartment of Chemistry , University of Rochester , Rochester , New York 14627 , USA . Email: matson@chem.rochester.edu.ORCID 0000-0002-7526-2385
R L MeyerDepartment of Chemistry , University of Rochester , Rochester , New York 14627 , USA . Email: matson@chem.rochester.edu.ORCID 0000-0003-2832-1458
S H CarpenterDepartment of Chemistry , University of Rochester , Rochester , New York 14627 , USA . Email: matson@chem.rochester.edu.
L E VanGelderDepartment of Chemistry , University of Rochester , Rochester , New York 14627 , USA . Email: matson@chem.rochester.edu.
A W NicholsDepartment of Chemistry , University of Virginia , Charlottesville , Virginia 22904-4319 , USA.
C W MachanDepartment of Chemistry , University of Virginia , Charlottesville , Virginia 22904-4319 , USA.ORCID 0000-0002-5182-1138
M L NeidigDepartment of Chemistry , University of Rochester , Rochester , New York 14627 , USA . Email: matson@chem.rochester.edu.
E M MatsonDepartment of Chemistry , University of Rochester , Rochester , New York 14627 , USA . Email: matson@chem.rochester.edu.ORCID 0000-0003-3753-8288

Funding

No grant is acknowledged in the PubMed record.

6 · The paper itself

Abstract

A series of NO-bound, iron-functionalized polyoxovanadate-alkoxide (FePOV-alkoxide) clusters have been synthesized, providing insight into the role of multimetallic constructs in the coordination and activation of a substrate. Upon exposure of the heterometallic cluster to NO, the vanadium-oxide metalloligand is oxidized by a single electron, shuttling the reducing equivalent to the {FeNO} subunit to form a {FeNO}

Identifiers

PMID30310566
PMCPMC6115649

What OpenQuestion holds

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Registered trials

None linked

Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.