Evidence map›Paper›PMID 30279417›Full record

ArticleNature communications2018

Dye-incorporated coordination polymers for direct photocatalytic trifluoromethylation of aromatics at metabolically susceptible positions.

Tiexin Zhang, Xiangyang Guo, Yusheng Shi, Cheng He, Chunying Duan

Abstract read
In one paragraph

Article in Nature communications, 2018. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 7 papers.

0numbers the graph read from it
0cells of the map it votes in
7citing papers in PubMed
–field-weighted citation impact
1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

The trial behind it

Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.

Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.

3 · Its place in the literature

Who cites it

7 citing papers in PubMed.

  1. Review
  2. Article
  3. Article
  4. Article
  5. Article
  6. Electrophotocatalytic Undirected C-H Trifluoromethylations of (Het)Arenes.Chemistry (Weinheim an der Bergstrasse, Germany) · 2020
    Article
  7. Article
4 · The record

Corrections and comments

PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.

5 · Who and what money

Authors and funding

5 authors.

Tiexin ZhangState Key Laboratory of Fine Chemicals, Dalian University of Technology, Dalian, 116024, China.
Xiangyang GuoState Key Laboratory of Fine Chemicals, Dalian University of Technology, Dalian, 116024, China.
Yusheng ShiState Key Laboratory of Fine Chemicals, Dalian University of Technology, Dalian, 116024, China.
Cheng HeState Key Laboratory of Fine Chemicals, Dalian University of Technology, Dalian, 116024, China.
Chunying DuanState Key Laboratory of Fine Chemicals, Dalian University of Technology, Dalian, 116024, China. cyduan@dlut.edu.cn.ORCID http://orcid.org/0000-0003-1638-6633

Funding

National Natural Science Foundation of China (National Science Foundation of China) 21402020National Natural Science Foundation of China (National Science Foundation of China) 21531001National Natural Science Foundation of China (National Science Foundation of China) U1608224
6 · The paper itself

Abstract

Direct trifluoromethylation of unactivated aromatic rings at metabolically susceptible positions is highly desirable in pharmaceutical applications. By incorporating thiophenes into the backbone of triphenylamine to enlarge its π-system, a new approach for constructing coordination polymers is reported for direct trifluoromethylation without prefunctionalization of the aryl precursors. The improved light-harvesting ability and well-modulated excited state redox potential of the designed polymers endow the generated CF

Indexed as

HalogenationHydrocarbons, AromaticMethylationThiophenesHydrocarbons, AromaticThiophenes

Identifiers

PMID30279417
PMCPMC6168478

What OpenQuestion holds

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Registered trials

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Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.