ArticleNanomaterials (Basel, Switzerland)2018
Resistance of Superhydrophobic Surface-Functionalized TiO₂ Nanotubes to Corrosion and Intense Cavitation.
Article in Nanomaterials (Basel, Switzerland), 2018. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 6 papers.
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Who cites it
6 citing papers in PubMed.
- Development of Novel Colorful Electrorheological Fluids.Nanomaterials (Basel, Switzerland) · 2022Article
- Surface Dissociation Effect on Phosphonic Acid Self-Assembled Monolayer Formation on ZnO Nanowires.ACS omega · 2022Article
- Gradient 3D Printed PLA Scaffolds on Biomedical Titanium: Mechanical Evaluation and Biocompatibility.Polymers · 2021Article
- Fabrication and Evaluation of Nano-TiOMaterials (Basel, Switzerland) · 2021Article
- Hydrophobicity Improvement of Cement-Based Materials Incorporated with Ionic Paraffin Emulsions (IPEs).Materials (Basel, Switzerland) · 2020Article
- Robust Polymer Nanocomposite Membranes Incorporating Discrete TiONanomaterials (Basel, Switzerland) · 2019Article
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Authors and funding
7 authors.
Funding
Abstract
The availability of robust superhydrophobic materials with the ability to withstand harsh environments are in high demand for many applications. In this study, we have presented a simple method to fabricate superhydrophobic materials from TiO₂ nanotube arrays (TNTAs) and investigated the resilience of the materials when they are subjected to harsh conditions such as intense cavitation upon ultrasonication, corrosion in saline water, water-jet impact, and abrasion. The TNTAs were prepared by anodization of Ti foil in buffered aqueous electrolyte containing fluoride ions. The hydrophilic TNTAs were functionalized with octadecylphosphonic acid (ODPA) or 1H, 1H', 2H, 2H'-perfluorodecyl phosphonic acid (PFDPA) to form a self-assembled monolayer on the TNTA surface to produce superhydrophobic ODPA@TNTA or PFDPA@TNTA surfaces. The superhydrophobic ODPA@TNTA and PFDPA@TNTA have contact angles of 156.0° ± 1.5° and 168° ± 1.5°, and contact angle hysteresis of 3.0° and 0.8°, respectively. The superhydrophobic ODPA@TNTA and PFDPA@TNTA were subjected to ultrasonication, corrosion in saline water, and water-jet impact and abrasion, and the resilience of the systems was characterized by electrochemical impedance spectroscopy (EIS), contact angle (CA) measurements, diffuse reflectance Fourier transform infrared spectroscopy (DRIFTS), and field-emission scanning electron microscopy (FESEM). The results presented here show that superhydrophobic ODPA@TNTA and PFDPA@TNTA are robust and resilient under the harsh conditions studied in this work, and indicate the potential of these materials to be deployed in practical applications.
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