ArticleACS central science2018
On Demand Switching of Polymerization Mechanism and Monomer Selectivity with Orthogonal Stimuli.
Article in ACS central science, 2018. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 16 papers.
What it found
Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.
The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.
The trial behind it
Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.
Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.
Who cites it
16 citing papers in PubMed.
- Combining photocontrolled-cationic and anionic-group-transfer polymerizations using a universal mediator: enabling access to two- and three-mechanism block copolymers.Chemical science · 2024Article
- Controlled switching thiocarbonylthio end-groups enables interconvertible radical and cationic single-unit monomer insertions and RAFT polymerizations.Nature communications · 2024Article
- Recent Developments on Cationic Polymerization of Vinyl Ethers.ACS polymers Au · 2024Review
- Near-Infrared Light-Induced Reversible Deactivation Radical Polymerization: Expanding Frontiers in Photopolymerization.Advanced science (Weinheim, Baden-Wurttemberg, Germany) · 2023Review
- Switchable DNA Photocatalysts for Radical Polymerization Controlled by Chemical Stimuli.Journal of the American Chemical Society · 2023Article
- Rational Design of Photocatalysts for Controlled Polymerization: Effect of Structures on Photocatalytic Activities.Chemical reviews · 2022Review
- Reversible redox controlled acids for cationic ring-opening polymerization.Chemical science · 2021Article
- Wavelength-Selective Photopolymerization of Hybrid Acrylate-Oxetane Liquid Crystals.Angewandte Chemie (International ed. in English) · 2021Article
- Rapid High-Resolution Visible Light 3D Printing.ACS central science · 2020Article
- Printing Precise Materials with Visible Light.ACS central science · 2020Article
- Mixed Polymer Brushes for "Smart" Surfaces.Polymers · 2020Review
- Polymer Nanofibers Exhibiting Remarkable Activity in Driving the Living Polymerization under Visible Light and Reusability.Advanced science (Weinheim, Baden-Wurttemberg, Germany) · 2020Article
- Tailoring polymer dispersity and shape of molecular weight distributions: methods and applications.Chemical science · 2019Review
- Controlled Cationic Polymerization: Single-Component Initiation under Ambient Conditions.Journal of the American Chemical Society · 2019Article
- PET-RAFT Polymerization Catalyzed by Small Organic Molecule under Green Light Irradiation.Polymers · 2019Article
- Next-Generation Materials via Orthogonal Stimuli.ACS central science · 2018Article
Corrections and comments
PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.
Authors and funding
4 authors.
Funding
No grant is acknowledged in the PubMed record.
Abstract
The development of next-generation materials is coupled with the ability to predictably and precisely synthesize polymers with well-defined structures and architectures. In this regard, the discovery of synthetic strategies that allow on demand control over monomer connectivity during polymerization would provide access to complex structures in a modular fashion and remains a grand challenge in polymer chemistry. In this Article, we report a method where monomer selectivity is controlled during the polymerization by the application of two orthogonal stimuli. Specifically, we developed a cationic polymerization where polymer chain growth is controlled by a chemical stimulus and paired it with a compatible photocontrolled radical polymerization. By alternating the application of the chemical and photochemical stimuli the incorporation of vinyl ethers and acrylates could be dictated by switching between cationic and radical polymerization mechanisms, respectively. This enables the synthesis of multiblock copolymers where each block length is governed by the amount of time a stimulus is applied, and the quantity of blocks is determined by the number of times the two stimuli are toggled. This new method allows on demand control over polymer structure with external influences and highlights the potential for using stimuli-controlled polymerizations to access novel materials.
Identifiers
What OpenQuestion holds
Registered trials
Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.