Evidence map›Paper›PMID 30254259›Full record

ArticleNature communications2018

Chirality amplification by desymmetrization of chiral ligand-capped nanoparticles to nanorods quantified in soft condensed matter.

Ahlam Nemati, Sasan Shadpour, Lara Querciagrossa, Lin Li, Taizo Mori, Min Gao, Claudio Zannoni, Torsten Hegmann

Open access · goldAbstract read
In one paragraph

Article in Nature communications, 2018. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 16 papers.

0numbers the graph read from it
0cells of the map it votes in
16citing papers in PubMed
3.7field-weighted citation impact, top 6% of its field
1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

The trial behind it

Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.

Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.

3 · Its place in the literature

Who cites it

16 citing papers in PubMed, 99 citations in OpenAlex.

  1. Article
  2. Article
  3. Review
  4. Article
  5. Chiral nanocrystals grown from MoSNature communications · 2022
    Article
  6. Review
  7. Article
  8. Article
  9. Article
  10. Review
  11. Article
  12. Article
  13. Article
  14. Article
  15. Chiral Supraparticles for Controllable Nanomedicine.Advanced materials (Deerfield Beach, Fla.) · 2020
    Article
  16. Article
4 · The record

Corrections and comments

PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.

5 · Who and what money

Authors and funding

8 authors at 4 institutions in 4 countries.

Ahlam NematiChemical Physics Interdisciplinary Program, Liquid Crystal Institute, Kent State University, Kent, OH, 44242-0001, USA.
Sasan ShadpourChemical Physics Interdisciplinary Program, Liquid Crystal Institute, Kent State University, Kent, OH, 44242-0001, USA.
Lara QuerciagrossaDipartimento di Chimica Industriale "Toso Montanari" and INSTM, Università di Bologna, Viale Risorgimento 4, IT-40136, Bologna, Italy.
Lin LiInstitute for Smart Liquid Crystals, JITRI, Changshu, 215500, Jiangsu, China.
Taizo MoriCenter for Materials Nanoarchitectonics (MANA), National Institute for Materials Science (NIMS), 1-1 Namiki, Tsukuba, Ibaraki, 305-0044, Japan.
Min GaoChemical Physics Interdisciplinary Program, Liquid Crystal Institute, Kent State University, Kent, OH, 44242-0001, USA.
Claudio ZannoniDipartimento di Chimica Industriale "Toso Montanari" and INSTM, Università di Bologna, Viale Risorgimento 4, IT-40136, Bologna, Italy.
Torsten HegmannChemical Physics Interdisciplinary Program, Liquid Crystal Institute, Kent State University, Kent, OH, 44242-0001, USA. thegmann@kent.edu.ORCID http://orcid.org/0000-0002-6664-6598
Kent State University · USUniversity of Bologna · ITJiangsu Industry Technology Research Institute · CNNational Institute for Materials Science · JP

Funding

NSF | Directorate for Mathematical & Physical Sciences | Division of Materials Research (DMR) DMR-1506018
6 · The paper itself

Abstract

Induction, transmission, and manipulation of chirality in molecular systems are well known, widely applied concepts. However, our understanding of how chirality of nanoscale entities can be controlled, measured, and transmitted to the environment is considerably lacking behind. Future discoveries of dynamic assemblies engineered from chiral nanomaterials, with a specific focus on shape and size effects, require exact methods to assess transmission and amplification of nanoscale chirality through space. Here we present a remarkably powerful chirality amplification approach by desymmetrization of plasmonic nanoparticles to nanorods. When bound to gold nanorods, a one order of magnitude lower number of chiral molecules induces a tighter helical distortion in the surrounding liquid crystal-a remarkable amplification of chirality through space. The change in helical distortion is consistent with a quantification of the change in overall chirality of the chiral ligand decorated nanomaterials differing in shape and size as calculated from a suitable pseudoscalar chirality indicator.

Identifiers

PMID30254259
PMCPMC6156227
OpenAlexW2891041739

What OpenQuestion holds

Textmetadata
LicenceCC BY
Read underepoch 390

Registered trials

None linked

Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.