ArticleAdvanced science (Weinheim, Baden-Wurttemberg, Germany)2018
Robust Sandwich-Structured Nanofluidic Diodes Modulating Ionic Transport for an Enhanced Electrochromic Performance.
Article in Advanced science (Weinheim, Baden-Wurttemberg, Germany), 2018. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 6 papers.
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Who cites it
6 citing papers in PubMed.
- Aqueous/non-aqueous electrolyte tradeoffs in charge transfer and electrochromics of pseudocapacitive oxide films.RSC advances · 2022Article
- Emerging Zn Anode-Based Electrochromic Devices.Small science · 2021Article
- Rational ion transport management mediated through membrane structures.Exploration (Beijing, China) · 2021Review
- Construction of Metal-Organic Frameworks (MOFs)-Based Membranes and Their Ion Transport Applications.Small science · 2021Article
- One-DimensionalAdvanced science (Weinheim, Baden-Wurttemberg, Germany) · 2020Article
- Robust Sandwich-Structured Nanofluidic Diodes Modulating Ionic Transport for an Enhanced Electrochromic Performance.Advanced science (Weinheim, Baden-Wurttemberg, Germany) · 2018Article
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Authors and funding
7 authors.
Funding
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Abstract
Biomimetic solid-state nanofluidic diodes have attracted extensive research interest due to the possible applications in various fields, such as biosensing, energy conversion, and nanofluidic circuits. However, contributions of exterior surface to the transmembrane ionic transport are often ignored, which can be a crucial factor for ion rectification behavior. Herein, a rational design of robust sandwich-structured nanofluidic diode is shown by creating opposite charges on the exterior surfaces of a nanoporous membrane using inorganic oxides with distinct isoelectric points. Potential-induced changes in ion concentration within the nanopores lead to a current rectification; the results are subsequently supported by a theoretical simulation. Except for providing surface charges, functional inorganic oxides used in this work are complementary electrochromic materials. Hence, the sandwich-structured nanofluidic diode is further developed into an electrochromic membrane exhibiting a visual color change in response to redox potentials. The results show that the surface-charge-governed ionic transport and the nanoporous structure facilitate the migration of Li
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