Evidence map›Paper›PMID 30234963›Full record

ArticleAccounts of chemical research2018

A Continuum of Proton-Coupled Electron Transfer Reactivity.

Julia W Darcy, Brian Koronkiewicz, Giovanny A Parada, James M Mayer

Abstract read
In one paragraph

Article in Accounts of chemical research, 2018. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 70 papers.

0numbers the graph read from it
0cells of the map it votes in
70citing papers in PubMed
–field-weighted citation impact
1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

The trial behind it

Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.

Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.

3 · Its place in the literature

Who cites it

70 citing papers in PubMed.

  1. Proton-Coupled Electron Transfer in Reaction of Catecholamines: Experimental and Computational Approach.Chemphyschem : a European journal of chemical physics and physical chemistry · 2026
    Article
  2. Acetylene Semi-Hydrogenation by Photocatalysis.Angewandte Chemie (International ed. in English) · 2026
    Review
  3. Review
  4. Mapping Proton-Coupled Electron Transfer With Real Space Coordinates.Angewandte Chemie (International ed. in English) · 2026
    Article
  5. Article
  6. Article
  7. Article
  8. Article
  9. Review
  10. Article
  11. Review
  12. Article
  13. Review
  14. On the mechanism of photodriven hydrogenations of NProceedings of the National Academy of Sciences of the United States of America · 2025
    Article
  15. Article
  16. Article
  17. Disentangling Driving Force Effects, Polar Effects,Journal of the American Chemical Society · 2025
    Article
  18. Article
  19. Article
  20. Article

10 more citing papers are in PubMed but not listed here.

4 · The record

Corrections and comments

PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.

5 · Who and what money

Authors and funding

4 authors.

Julia W DarcyDepartment of Chemistry , Yale University , New Haven , Connecticut 06520-8107 , United States.ORCID 0000-0003-0633-8187
Brian KoronkiewiczDepartment of Chemistry , Yale University , New Haven , Connecticut 06520-8107 , United States.
Giovanny A ParadaDepartment of Chemistry , Yale University , New Haven , Connecticut 06520-8107 , United States.
James M MayerDepartment of Chemistry , Yale University , New Haven , Connecticut 06520-8107 , United States.ORCID 0000-0002-3943-5250

Funding

UNDERSTANDING METAL MEDIATED C-H AND O-H BOND OXIDATIONSR01GM050422 · NIGMS · YALE UNIVERSITY · PI MAYER, JAMES M · 1995 to 2020
$6.1M
Understanding coupled transfers of electrons and protons relevant to biological cR56GM050422 · NIGMS · UNIVERSITY OF WASHINGTON · PI MAYER, JAMES M · 2007 to 2007
$310k
NIGMS NIH HHS R01 GM050422NIGMS NIH HHS R56 GM050422
6 · The paper itself

Abstract

Proton-coupled electron transfer (PCET) covers a wide range of reactions involving the transfer(s) of electrons and protons. The best-known PCET reaction, hydrogen atom transfer (HAT), has been studied in detail for more than a century. HAT is generally described as the concerted transfer of a hydrogen atom (H

Indexed as

CarbonCoordination ComplexesElectronsElectron TransportHydrogenHydrogen BondingHydroxylamineKineticsOxidation-ReductionPhenolsProtonsRutheniumThermodynamicsCarbonCoordination ComplexesHydrogenHydroxylaminePhenolsProtonsRuthenium

Identifiers

PMID30234963
PMCPMC6197915

What OpenQuestion holds

Textmetadata
LicenceTDM
Read underepoch 390

Registered trials

None linked

Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.