ArticleThe European physical journal. E, Soft matter2018
Phase behaviour of colloidal superballs mixed with non-adsorbing polymers.
Article in The European physical journal. E, Soft matter, 2018. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 1 paper.
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1 citing paper in PubMed.
- Phase stability of dispersions of hollow silica nanocubes mediated by non-adsorbing polymers.The European physical journal. E, Soft matter · 2020Article
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3 authors.
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Abstract
Inspired by experimental work on colloidal cuboid-polymer dispersions (Rossi et al., Soft Matter, 7, 4139 (2011)) we have theoretically studied the phase behaviour of such mixtures. To that end, free volume theory (FVT) was applied to predict the phase behaviour of mixtures of superballs and non-adsorbing polymer chains in a common solvent. Closed expressions for the thermodynamic properties of a suspension of hard colloidal superballs have been derived, accounting for fluid (F), face-centred cubic (FCC) and simple cubic (SC) phase states. Even though the considered solid phases are approximate, the hard superballs phase diagram semi-quantitatively matches with more evolved methods. The theory developed for the cuboid-polymer mixture reveals a rich phase behaviour, which includes not only isostructural F
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