ArticleJournal of the American Chemical Society2018
Polymorphism in Benzene-1,3,5-tricarboxamide Supramolecular Assemblies in Water: A Subtle Trade-off between Structure and Dynamics.
Article in Journal of the American Chemical Society, 2018. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 28 papers.
What it found
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The trial behind it
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Who cites it
28 citing papers in PubMed.
- Pathway Complexity in Naphthalene Diimide Supramolecular Polymers: Interruption by an Aromatic Solvent.Chemistry (Weinheim an der Bergstrasse, Germany) · 2026Article
- Linker Molar Mass-Driven Control over Supramolecular Network Relaxation and Architecture in BTA Hydrogels.Macromolecules · 2026Article
- Thermally Controlled Chiral Supramolecular Polymorphism in Water.Angewandte Chemie (International ed. in English) · 2026Article
- One- and Two-Dimensional Polymorphism in a Hydrogen-Bonding Bis-Ureido-Squaramide.Angewandte Chemie (International ed. in English) · 2026Article
- Selective Activation of Dynamics in Kinetically Frozen Supramolecular Polymer Bottlebrush Assemblies.Small (Weinheim an der Bergstrasse, Germany) · 2025Article
- Article
- Balancing Chemical and Supramolecular Stability in OEGylated Supramolecular Polymers for Systemic Drug Delivery.Journal of the American Chemical Society · 2025Article
- Using Chemistry To Recreate the Complexity of the Extracellular Matrix: Guidelines for Supramolecular Hydrogel-Cell Interactions.Journal of the American Chemical Society · 2024Review
- Dual-Responsive Supramolecular Chiral Assemblies from Amphiphilic Dendronized Tetraphenylethylenes.Molecules (Basel, Switzerland) · 2023Article
- Impact of sample history and solvent effects on pathway control in the supramolecular polymerisation of Au(i)-metallopeptide amphiphiles.Polymer chemistry · 2023Article
- Micelle and Nanotape Formation of Benzene Tricarboxamide Analogues with Selective Cancer Cell Cytotoxicity.ACS omega · 2022Article
- Selection of diverse polymorphic structures from a small dynamic molecular network controlled by the environment.Chemical science · 2022Article
- Thermoreversible Polymorph Transitions in Supramolecular Polymers of Hydrogen-Bonded Squaramides.Angewandte Chemie (International ed. in English) · 2022Article
- Photo-modulation of supramolecular polymorphism in the self-assembly of a scissor-shaped azobenzene dyad into nanotoroids and fibers.Chemical science · 2022Article
- Desymmetrization via Activated Esters Enables Rapid Synthesis of Multifunctional Benzene-1,3,5-tricarboxamides and Creation of Supramolecular Hydrogelators.Journal of the American Chemical Society · 2022Article
- Unveiling Polymerization Mechanism in pH-regulated Supramolecular Fibers in Aqueous Media.Chemistry (Weinheim an der Bergstrasse, Germany) · 2021Article
- Polymorphism in Squaraine Dye Aggregates by Self-Assembly Pathway Differentiation: Panchromatic Tubular Dye Nanorods versus J-Aggregate Nanosheets.Angewandte Chemie (International ed. in English) · 2021Article
- Tuning the Molecular Packing of Self-Assembled Amphiphilic PtChemistry (Weinheim an der Bergstrasse, Germany) · 2021Article
- Pathway and Length Control of Supramolecular Polymers in Aqueous Media via a Hydrogen Bonding Lock.Angewandte Chemie (International ed. in English) · 2021Article
- Control over size, shape, and photonics of self-assembled organic nanocrystals.Beilstein journal of organic chemistry · 2021Article
Corrections and comments
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Authors and funding
11 authors.
Funding
No grant is acknowledged in the PubMed record.
Abstract
In biology, polymorphism is a well-known phenomenon by which a discrete biomacromolecule can adopt multiple specific conformations in response to its environment. The controlled incorporation of polymorphism into noncovalent aqueous assemblies of synthetic small molecules is an important step toward the development of bioinspired responsive materials. Herein, we report on a family of carboxylic acid functionalized water-soluble benzene-1,3,5-tricarboxamides (BTAs) that self-assemble in water to form one-dimensional fibers, membranes, and hollow nanotubes. Interestingly, one of the BTAs with the optimized position of the carboxylic group in the hydrophobic domain yields nanotubes that undergo reversible temperature-dependent dynamic reorganizations. SAXS and Cryo-TEM data show the formation of elongated, well-ordered nanotubes at elevated temperatures. At these temperatures, increased dynamics, as measured by hydrogen-deuterium exchange, provide enough flexibility to the system to form well-defined nanotube structures with apparently defect-free tube walls. Without this flexibility, the assemblies are frozen into a variety of structures that are very similar at the supramolecular level, but less defined at the mesoscopic level.
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Registered trials
Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.